Plumbylene
Plumbylenes (or plumbylidenes) are divalent organolead(II) analogues of carbenes, with the general chemical formula, R2Pb, where R denotes a substituent. Plumbylenes possess 6 electrons in their valence shell, and are considered open shell species. The first plumbylene reported was the dialkylplumbylene, [(Me3Si)2CH]2Pb, which was synthesized by Michael F. Lappert et al in 1973. Plumbylenes may be further classified into carbon-substituted plumbylenes, plumbylenes stabilized by a group 15 or 16 element, and monohalogenated plumbylenes (RPbX).
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Plumbylene
Plumbylenes (or plumbylidenes) are divalent organolead(II) analogues of carbenes, with the general chemical formula, R2Pb, where R denotes a substituent. Plumbylenes possess 6 electrons in their valence shell, and are considered open shell species. The first plumbylene reported was the dialkylplumbylene, [(Me3Si)2CH]2Pb, which was synthesized by Michael F. Lappert et al in 1973. Plumbylenes may be further classified into carbon-substituted plumbylenes, plumbylenes stabilized by a group 15 or 16 element, and monohalogenated plumbylenes (RPbX).
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Plumbylenes (or plumbylidenes) ...... alogenated plumbylenes (RPbX).
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February 2019
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. Agostic interactions are hig ...... ith a red dot in the top view.
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Example of plumbylene stabiliz ...... om in side-arm of substituent;
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Examples of plumbylenes exhibi ...... of X-ray crystal structure of
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Molecular orbitals and natural bond orbitals of diphenyllead
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[2,4,6-3C6H2]2Pb
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[{3P}CH]3Pb
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and its X-ray structure showin ...... oms in substituents to Pb atom
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AIM is intrinsically computati ...... cal point pretty much assumed?
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Plumbylenes (or plumbylidenes) ...... alogenated plumbylenes (RPbX).
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Plumbylene
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