Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
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Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactionsA reaction mode of carbene-catalysed aryl aldehyde activation and induced phenol OH functionalization.Continuous-Flow N-Heterocyclic Carbene Generation and Organocatalysis.Asymmetric Organocatalysis: The Emerging Utility of α,β-Unsaturated Acylammonium Salts.Radical [1,3] Rearrangements of Breslow Intermediates.Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process.Insights into the Competing Mechanisms and Origin of Enantioselectivity for N-Heterocyclic Carbene-Catalyzed Reaction of Aldehyde with Enamide.Organocatalytic activation of isocyanides: N-heterocyclic carbene-catalyzed enaminone synthesis from ketones.N-Heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindoles and enals: cross coupling of homoenolate and enolate.Enantioselective syntheses of indanes: from organocatalysis to C-H functionalization.The Need for an Alternative to Radicals as the Cause of Fragmentation of a Thiamin-Derived Breslow Intermediate.α,α-Dicyanoolefins: versatile substrates in organocatalytic asymmetric transformations.Promotion of Organic Reactions by Non-Benzenoid Carbocyclic Aromatic Ions.Azidoimidazolinium Salts: Safe and Efficient Diazo-transfer Reagents and Unique Azido-donors.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Recent advances in N-heterocyclic carbene catalyzed achiral synthesis.Privileged chiral N-heterocyclic carbene ligands for asymmetric transition-metal catalysis.NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones.Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from EnalsEfficient synthetic protocols for the preparation of common N-heterocyclic carbene precursorsAsymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction.Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniumsElectron-transfer-initiated benzoin- and Stetter-like reactions in packed-bed reactors for process intensification.Alkene Photo-Isomerization Inspired by VisionExperimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects.Merging N-Heterocyclic Carbene Catalysis and Single Electron Transfer: A New Strategy for Asymmetric Transformations.Oxygen Atom Transfer Using an Iron(IV)-Oxo Embedded in a Tetracyclic N-Heterocyclic Carbene System: How Does the Reactivity Compare to Cytochrome P450 Compound I?A mesoionic bis(Py-tzNHC) palladium(II) complex catalyses "green" Sonogashira reaction through an unprecedented mechanism.N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes.Oxidative organocatalytic chemoselective N-acylation of heterocycles with aromatic and conjugated aldehydes.Catalytic Asymmetric Synthesis of Chiral γ-Amino Ketones via Umpolung Reactions of Imines.N-Heterocyclic carbene-catalyzed sulfa-Michael addition of enals.An Ir-photoredox-catalyzed decarboxylative Michael addition of glyoxylic acid acetal as a formyl equivalent.Optically active histidin-2-ylidene stabilised gold nanoparticles.Organocatalytic Highly Regio- and Enantioselective Umpolung Michael Addition Reaction of α-Imino Esters.Construction of Fused Pyrrolidines and β-Lactones by Carbene-Catalyzed C-N, C-C, and C-O Bond Formations.Polyhalides as Efficient and Mild Oxidants for Oxidative Carbene Organocatalysis by Radical Processes.Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes.C-F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene.Accessing Stable Magnesium Acyl Compounds: Reductive Cleavage of Esters by Magnesium(I) Dimers.
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P2860
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
description
2015 nî lūn-bûn
@nan
2015 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած
@hyw
2015 թվականի սեպտեմբերին հրատարակված գիտական հոդված
@hy
2015年の論文
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2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
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name
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@ast
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@en
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@nl
type
label
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@ast
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@en
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@nl
prefLabel
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@ast
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@en
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@nl
P2093
P2860
P3181
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P1476
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes
@en
P2093
Darrin M. Flanigan
Fedor Romanov-Michailidis
Nicholas A. White
P2860
P304
P3181
P356
10.1021/ACS.CHEMREV.5B00060
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P577
2015-09-09T00:00:00Z