Recent developments in the field of oxa-Michael reactions.
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Contemporary Strategies for the Synthesis of Tetrahydropyran Derivatives: Application to Total Synthesis of Neopeltolide, a Marine Macrolide Natural ProductStructure and catalytic mechanism of the evolutionarily unique bacterial chalcone isomeraseEnantioselective copper-catalyzed carboetherification of unactivated alkenes.Concise synthesis and biological assessment of (+)-neopeltolide and a 16-member stereoisomer library of 8,9-dehydroneopeltolide: identification of pharmacophoric elements.Synthesis of a Library of 1,5,2-Dithiazepine 1,1-Dioxides. Part 1: A One-Pot Sulfonylation/Thia-Michael Protocol.Gold (III) Chloride-Catalyzed 6-endo-trig Oxa-Michael Addition Reactions for Diastereoselective Synthesis of Fused Tetrahydropyranones.Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols.Enantioselective synthesis of hindered cyclic dialkyl ethers via catalytic oxa-Michael/Michael desymmetrization.Sequential catalysis for stereoselective synthesis of complex polyketides.Recent advances in C-heteroatom bond forming by asymmetric Michael addition.Synthesis and Application of [3.3.0]Furofuranone in Total Synthesis.Stereoselective total synthesis and structural elucidation of (-)-indoxamycins A-F.A mild, diastereoselective construction of cyclic and spirocyclic ketals employing a tandem photoisomerization/cyclization tactic.Asymmetric organocatalytic methods for the synthesis of tetrahydropyrans and their application in total synthesis.An asymmetric synthesis of 1,2,4-trioxane anticancer agents via desymmetrization of peroxyquinols through a Brønsted acid catalysis cascade.Catalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis.Coupling of carboxylic acids with internal alkynes by supported ruthenium catalysts: direct and selective syntheses of multi-substituted phthalide derivatives.4-Hydroxy-6-alkyl-2-pyrones as nucleophilic coupling partners in Mitsunobu reactions and oxa-Michael additionsEnantioselective Michael addition of water.The stereodivergent formation of 2,6-cis and 2,6-trans-tetrahydropyrans: experimental and computational investigation of the mechanism of a thioester oxy-Michael cyclization.A versatile and efficient approach for the synthesis of chiral 1,3-nitroamines and 1,3-diamines via conjugate addition to new (S,E)-γ-aminated nitroalkenes derived from L-α-amino acids.Catalytic asymmetric formal synthesis of beraprost.Racemic hemiacetals as oxygen-centered pronucleophiles triggering cascade 1,4-addition/Michael reaction through dynamic kinetic resolution under iminium catalysis. Development and mechanistic insights.Design of an enantioselective artificial metallo-hydratase enzyme containing an unnatural metal-binding amino acid.Inner workings of a cinchona alkaloid catalyzed oxa-Michael cyclization: evidence for a concerted hydrogen-bond-network mechanism.Facile access to cis-2,6-disubstituted tetrahydropyrans by palladium-catalyzed decarboxylative allylation: total syntheses of (±)-centrolobine and (+)-decytospolides A and B.Efficient copper-catalyzed Michael addition of acrylic derivatives with primary alcohols in the presence of base.A powerful hydrogen-bond-donating organocatalyst for the enantioselective intramolecular oxa-Michael reaction of α,β-unsaturated amides and esters.Highly enantioselective sulfa-Michael addition reactions using N-heterocyclic carbene as a non-covalent organocatalyst.Biomimetic Total Synthesis of (±)-Verrubenzospirolactone.Total synthesis of (+)-herboxidiene/GEX 1A.AgOTf-catalyzed sequential synthesis of 4-isoquinolones via oxidative ring opening of aziridines and aza-Michael addition.FeCl3-catalyzed dimerization/elimination of 1,1-diarylalkenes: efficient synthesis of functionalized 4H-chromenes.Chiral phosphoric acid catalyzed enantioselective annulation of acyclic enecarbamates to in situ-generated ortho-quinone methides.Green chemistry: solvent- and metal-free Prins cyclization. Application to sequential reactions.Stereodivergent Synthesis of Functionalized Tetrahydropyrans Accelerated by Mechanism-Based Allylboration and Bioinspired Oxa-Michael Cyclization.The asymmetric total synthesis of (+)-N-acetyl norloline.Phosphine-Catalyzed β,γ-Umpolung Domino Reaction of Allenic Esters: Facile Synthesis of Tetrahydrobenzofuranones Bearing a Chiral Tetrasubstituted Stereogenic Carbon Center.Enantioselective cascade double Michael addition of 3-nitro-2H-chromenes and acyclic enones: efficient synthesis of functionalized tricyclic chroman derivatives.Stereoselective construction of sterically hindered oxaspirocycles via chiral bidentate directing group-mediated C(sp3)-O bond formation.
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P2860
Recent developments in the field of oxa-Michael reactions.
description
article científic
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article scientifique
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articol științific
@ro
articolo scientifico
@it
artigo científico
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artigo científico
@pt
artigo científico
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artikel ilmiah
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artikull shkencor
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artículo científico
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name
Recent developments in the field of oxa-Michael reactions.
@en
Recent developments in the field of oxa-Michael reactions.
@nl
type
label
Recent developments in the field of oxa-Michael reactions.
@en
Recent developments in the field of oxa-Michael reactions.
@nl
prefLabel
Recent developments in the field of oxa-Michael reactions.
@en
Recent developments in the field of oxa-Michael reactions.
@nl
P2860
P356
P1476
Recent developments in the field of oxa-Michael reactions.
@en
P2093
Carl F Nising
Stefan Bräse
P2860
P304
P356
10.1039/C1CS15167C
P577
2011-07-28T00:00:00Z