Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation.
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A survey of sulfide ligands for allylic C-H oxidations of terminal olefins.Ligand-enabled reactivity and selectivity in a synthetically versatile aryl C-H olefinationPalladium-catalyzed regioselective azidation of allylic C-H bonds under atmospheric pressure of dioxygen.Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes.Development of a general, sequential, ring-closing metathesis/intramolecular cross-coupling reaction for the synthesis of polyunsaturated macrolactonesMolecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction.Diarylpropionitrile (DPN) enantiomers: synthesis and evaluation of estrogen receptor β-selective ligands.Illicium sesquiterpenes: divergent synthetic strategy and neurotrophic activity studiesEnantioselective Alcohol C-H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis.Non-Directed Allylic C-H Acetoxylation in the Presence of Lewis Basic Heterocycles.Enantioselective synthesis of (-)-jiadifenin, a potent neurotrophic modulatorAn approach to the site-selective deoxygenation of hydroxy groups based on catalytic phosphoramidite transferHarnessing C-H Activation of Benzhydroxamates as a Macrocyclization Strategy: Synthesis of Structurally Diverse Macrocyclic Isoquinolones.Palladium-Catalyzed C-H Arylation of α,β-Unsaturated Imines: Catalyst-Controlled Synthesis of Enamine and Allylic Amine Derivatives.Prins-type macrocyclizations as an efficient ring-closing strategy in natural product synthesis.Diastereotopos-differentiating C-H activation reactions at methylene groups.Transition metal catalysis and nucleophilic fluorination.Amide-directed tandem C-C/C-N bond formation through C-H activation.Polyketide construction via hydrohydroxyalkylation and related alcohol C-H functionalizations: reinventing the chemistry of carbonyl addition.Ester coupling reactions--an enduring challenge in the chemical synthesis of bioactive natural products.The emergence of sulfoxides as efficient ligands in transition metal catalysis.Synthetic versatility in C-H oxidation: a rapid approach to differentiated diols and pyrans from simple olefins.The Therapeutic Potential of Migrastatin-Core Analogs for the Treatment of Metastatic Cancer.Trends in applying C-H oxidation to the total synthesis of natural products.Scaffold Diversity Synthesis and Its Application in Probe and Drug Discovery.Synthesis of esters via sp(3) C-H functionalisation.Synthesis of Antibiotics.Promiscuity of a modular polyketide synthase towards natural and non-natural extender units.Total synthesis of 6-deoxyerythronolide B via C-C bond-forming transfer hydrogenationAerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition.Terminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed Wacker oxidation-dehydrogenation.Aliphatic C-H to C-C conversion: synthesis of (-)-cameroonan-7α-ol.Selective allylic hydroxylation of acyclic terpenoids by CYP154E1 from Thermobifida fusca YXRegio- and stereodivergent antibiotic oxidative carbocyclizations catalysed by Rieske oxygenase-like enzymes.Cationic palladium(II) catalysis: C-H activation/Suzuki-Miyaura couplings at room temperature.Biocatalytic synthesis of pikromycin, methymycin, neomethymycin, novamethymycin, and ketomethymycin.Synthesis of complex allylic esters via C-H oxidation vs C-C bond formation.Diversification of a β-Lactam Pharmacophore via Allylic C-H Amination: Accelerating Effect of Lewis Acid Co-Catalyst.An efficient palladium-catalyzed C-H alkoxylation of unactivated methylene and methyl groups with cyclic hypervalent iodine (i(3+) ) oxidants.A unified photoredox-catalysis strategy for C(sp3)-H hydroxylation and amidation using hypervalent iodine
P2860
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P2860
Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh
2009年學術文章
@zh-hant
name
Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation.
@en
type
label
Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation.
@en
prefLabel
Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation.
@en
P2860
P356
P1433
P1476
Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation.
@en
P2093
Erik M Stang
M Christina White
P2860
P2888
P304
P356
10.1038/NCHEM.351
P577
2009-08-30T00:00:00Z