Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
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1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysisEnantioselective construction of remote quaternary stereocentresEnantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement.Activation of alcohols with carbon dioxide: intermolecular allylation of weakly acidic pronucleophiles.Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones.A Cooperative N-Heterocyclic Carbene/Palladium Catalysis System.Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinonesCatalytic enantioselective synthesis of quaternary carbon stereocentresCopper-catalysed enantioselective stereodivergent synthesis of amino alcohols.Tandem Rh-catalysis: decarboxylative β-keto acid and alkyne cross-coupling.Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones.Synergistic chiral iminium and palladium catalysis: Highly regio- and enantioselective [3 + 2] annulation reaction of 2-vinylcyclopropanes with enalsArCH(OMe)₂--a Pt(IV)-catalyst originator for diverse annulation catalysis.Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary StereocentersIridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides.Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones.Synergy, compatibility, and innovation: merging Lewis acids with stereoselective enamine catalysis.Enantioselective cooperative catalysis.Catalytic Strategies for Diastereodivergent Synthesis.Synthesis of Phytocannabinoids.A highly efficient dual catalysis approach for C-glycosylation: addition of (o-azaaryl)carboxaldehyde to glycals.Chiral counteranion strategy for asymmetric oxidative C(sp³)-H/C(sp³)-H coupling: enantioselective α-allylation of aldehydes with terminal alkenes.Switchable divergent asymmetric synthesis via organocatalysis.Enantioselective Chemo- and Biocatalysis: Partners in Retrosynthesis.Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles.Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates.Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity.Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters.Congested C-C bonds by Pd-catalyzed enantioselective allyl-allyl cross-coupling, a mechanism-guided solution.Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysisComplete diastereodivergence in asymmetric 1,6-addition reactions enabled by minimal modification of a chiral catalyst.Stereodivergent, Diels-Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application.Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolatesCatalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters.Asymmetric fluorination of α-branched cyclohexanones enabled by a combination of chiral anion phase-transfer catalysis and enamine catalysis using protected amino acids.Organocatalytic and enantioselective Michael reaction between α-nitroesters and nitroalkenes. Syn/anti-selectivity control using catalysts with the same absolute backbone chirality.Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis.Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to α,β,γ,δ-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups.Chemistry. A new twist on cooperative catalysis.
P2860
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P2860
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
description
2013 nî lūn-bûn
@nan
2013 թուականի Մայիսին հրատարակուած գիտական յօդուած
@hyw
2013 թվականի մայիսին հրատարակված գիտական հոդված
@hy
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
name
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@ast
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@en
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@nl
type
label
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@ast
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@en
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@nl
prefLabel
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@ast
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@en
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@nl
P50
P356
P1433
P1476
Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
@en
P2093
Simon Krautwald
P304
P356
10.1126/SCIENCE.1237068
P407
P577
2013-05-01T00:00:00Z