Catalytic enantioselective 1,2-diboration of 1,3-dienes: versatile reagents for stereoselective allylation.
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Synthesis of medicinally relevant terpenes: reducing the cost and time of drug discovery.γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.Enantioselective synthesis of (Z)- and (E)-2-methyl-1,5-anti-pentenediols via an allene hydroboration-double-allylboration reaction sequence.Enantiodivergent Hydroboration Reactions of a Racemic Allenylsilane with Diisopinocampheylborane and Curtin-Hammett Controlled Double Asymmetric Crotylboration Reactions of (S)-E-α-phenyldimethylsilyl( (d) diisopinocampheyl)-crotylborane.Enantiodivergent hydroboration reactions of a racemic allenylsilane with diisopinocampheylborane and Curtin-Hammett controlled double asymmetric crotylboration reactions of (S)-E-αphenyldimethylsilyl( (d) diisopinocampheyl)-crotylborane.Selective carbon-carbon bond cleavage for the stereoselective synthesis of acyclic systems.Enantioselective desymmetrization via carbonyl-directed catalytic asymmetric hydroboration and Suzuki-Miyaura cross-coupling.A catalytic enantioselective tandem allylation strategy for rapid terpene construction: application to the synthesis of pumilaside aglyconCopper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to γ-hydroxyl boronic esters.Synthesis of Functionalized Hydrazines: Facile Homogeneous (N-Heterocyclic Carbene)-Palladium(0)-Catalyzed Diboration and Silaboration of Azobenzenes.Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates.Enantiomerically enriched tris(boronates): readily accessible conjunctive reagents for asymmetric synthesisMechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Regio- and Stereoselective Homologation of 1,2-Bis(Boronic Esters): Stereocontrolled Synthesis of 1,3-Diols and Sch 725674Nonracemic allylic boronates through enantiotopic-group-selective cross-coupling of geminal bis(boronates) and vinyl halides.Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and DiboranesSelective uni- and bidirectional homologation of diborylmethane.Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes.Scope and mechanism of the Pt-catalyzed enantioselective diboration of monosubstituted alkenesCatalytic enantioselective one-pot aminoborylation of aldehydes: a strategy for construction of nonracemic α-amino boronates.Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy estersEnantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Asymmetric diboration of terminal alkenes with a rhodium catalyst and subsequent oxidation: enantioselective synthesis of optically active 1,2-diols.Air-stable bifunctional allylation reagents for the asymmetric synthesis of differentiated syn- and anti-1,3-diols.Merging allylic carbon-hydrogen and selective carbon-carbon bond activation.Diastereodivergent synthesis of trisubstituted alkenes through protodeboronation of allylic boronic esters: application to the synthesis of the Californian red scale beetle pheromone.Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.Catalyst Controlled Regiodivergent Arylboration of Dienes.Enantioselective Intermolecular Addition of Aliphatic Amines to Acyclic Dienes with a Pd-PHOX Catalyst.Brook Rearrangement as a Trigger for the Ring Opening of Strained Carbocycles.Diels-Alder Reactions of 1,2-Azaborines.Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes.Rh(iii)-catalyzed C–H functionalization/aromatization cascade with 1,3-dienes: a redox-neutral and regioselective access to isoquinolinesStereoselective allylboration of imines and indoles under mild conditions. An in situ E/Z isomerization of imines by allylboroxines
P2860
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P2860
Catalytic enantioselective 1,2-diboration of 1,3-dienes: versatile reagents for stereoselective allylation.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@en
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@nl
type
label
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@en
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@nl
prefLabel
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@en
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@nl
P2093
P2860
P356
P1476
Catalytic enantioselective 1,2 ...... or stereoselective allylation.
@en
P2093
Grace E Ferris
James P Morken
Laura T Kliman
Scott N Mlynarski
P2860
P304
P356
10.1002/ANIE.201105716
P407
P577
2011-12-01T00:00:00Z