about
C-nucleosides: synthetic strategies and biological applications.The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes.Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron.On the selective N-methylation of BOC-protected amino acids.Soluble polymer-supported organocatalysts: asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid derived formamide anchored to a soluble polymer.Electrochemical recognition of chiral species using quaternary ammonium binaphthyl salts.Synthesis of new chiral 2,2'-bipyridine ligands and their application in copper-catalyzed asymmetric allylic oxidation and cyclopropanation.Synthesis of alpha-amino acids via asymmetric phase transfer-catalyzed alkylation of achiral nickel(II) complexes of glycine-derived Schiff bases.Chiral recognition in solution and the gas phase. Experimental and theoretical studies of aromatic D- and L-amino acid-Cu(II)-chiragen complexes.Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane.Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands.Polymer-supported organocatalysts: asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid-derived formamide anchored to a polymer.Amino acid-derived hydroxamic acids as chiral ligands in the vanadium catalysed epoxidation.Cross-Aldol Reaction of Isatin with Acetone Catalyzed by Leucinol: A Mechanistic Investigation.Corner opening of cyclopropanes by mercury(II) and thallium(III) and transmetalation of the intermediate organomercurials. A novel, stereoselective approach to cyclobutanes and cyclopropanesMolybdenum(V)-Mediated Skeletal Rearrangement of an Organomercury Steroid. Stereoelectronic Control and MechanismTransmetallation with palladium(II) of an organomercurial arising from mercury(II)-mediated cyclopropane cleavage. Tuning of the palladium reactivity and a novel, intramolecular redox reactionCorner attack on cyclopropane by thallium(III) ions. A highly stereospecific cleavage and skeletal rearrangement of 3.alpha.,5-cyclo-5.alpha.-cholestan-6.alpha.-olStructural requirements for the thallium(III)-mediated cyclisation of unsaturated alcohols. A novel fragmentation reaction producing 19-norsteroidsAsymmetric Allylic Substitution Catalyzed byC1-Symmetrical Complexes of Molybdenum: Structural Requirements of the Ligand and the Stereochemical Course of the Reaction2H-quadrupolar coupling-based analysis of stereochemical and regiochemical memory in the Pd-catalysed allylic alkylation of iso-cinnamyl type substrates employing the chiral monophosphine ligands ‘MOP’ and ‘MAP’Palladium(II) Complexes of 2-Dimethylamino-2‘- diphenylphosphino-1,1‘-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig−Buchwald Amination, and Suzuki CouplingVicinal Amino Alcohols as Organocatalysts in Asymmetric Cross-Aldol Reaction of Ketones: Application in the Synthesis of Convolutamydine A†Molybdenum(II)-Catalyzed Allylation of Electron-Rich Aromatics and HeteroaromaticsMolybdenum(II)- and Tungsten(II)-Catalyzed Allylic SubstitutionSteroids with modified ring A or B: screening for potential antiandrogenic and synandrogenic activityPINDY: A novel, pinene-derived bipyridine ligand and its application in asymmetric, Copper(I)-catalyzed allylic oxidationNon-symmetrically substituted 1,1'-binaphthyls in enantioselective catalysisQuinox, a quinoline-type N-oxide, as organocatalyst in the asymmetric allylation of aromatic aldehydes with allyltrichlorosilanes: the role of arene-arene interactionsRuthenium-Catalyzed Oppenauer-Type Oxidation of 3beta-Hydroxy Steroids. A Highly Efficient Entry into the Steroidal Hormones with 4-En-3-one FunctionalityAn Approach toward the Triquinane-Type Skeleton via Reagent-Controlled Skeletal Rearrangements. A Facile Method for Protection-Deprotection of Organomercurials, Tuning the Selectivity of Wagner-Meerwein Migrations, and a New Route to Annulated LactoNew Lewis-Acidic Molybdenum(II) and Tungsten(II) Catalysts for Intramolecular Carbonyl Ene and Prins Reactions. Reversal of the Stereoselectivity of Cyclization of CitronellalChiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilaneOrganocatalysis with a fluorous tag: asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamidesEnantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of alpha-chloroketonesRole of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilaneMETHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanesDynamic kinetic resolution in the asymmetric synthesis of beta-amino acids by organocatalytic reduction of enamines with trichlorosilaneSynthesis of enantiopure 1-arylprop-2-en-1-ols and their tert-butyl carbonatesRemote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines
P50
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P50
description
researcher ORCID ID = 0000-0002-1814-0939
@en
name
Pavel Kocovsky
@ast
Pavel Kocovsky
@en
Pavel Kocovsky
@es
Pavel Kocovsky
@nl
type
label
Pavel Kocovsky
@ast
Pavel Kocovsky
@en
Pavel Kocovsky
@es
Pavel Kocovsky
@nl
prefLabel
Pavel Kocovsky
@ast
Pavel Kocovsky
@en
Pavel Kocovsky
@es
Pavel Kocovsky
@nl
P1153
7004447818
P21
P31
P496
0000-0002-1814-0939