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Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand.Reversible Redox Chemistry and Catalytic C(sp(3))-H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand.Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole-Based Tripodal Tetraphosphine Ligand.Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity.Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes.Nitrene Radical Intermediates in Catalytic Synthesis.Catalyst recycling via specific non-covalent adsorption on modified silicas.Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex.Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium.Dynamic ligand reactivity in a rhodium pincer complex.C-H Activation of Benzene by a Photoactivated Ni(II)(azide): Formation of a Transient Nickel Nitrido Complex.Facile synthesis and versatile reactivity of an unusual cyclometalated rhodium(I) pincer complex.Dinuclear palladium complexes with two ligand-centered radicals and a single bridging ligand: subtle tuning of magnetic properties.Redox-active ligand-induced homolytic bond activation.Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)-Carbene Radical and ortho-Quinodimethane Intermediates.Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex.Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst.Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand.Intramolecular redox-active ligand-to-substrate single-electron transfer: radical reactivity with a palladium(II) complex.Reactivity of a mononuclear iridium(I) species bearing a terminal phosphido fragment embedded in a triphosphorus ligand.Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins.Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium.Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand.3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2 Coordination and Reduction and Formic Acid DehydrogenationReactivity of Me-pma RhIand IrIComplexes upon Deprotonation and Their Application in Catalytic Carbene Carbonylation ReactionsWell-Defined BisMETAMORPhos PdI–PdI Complex: Synthesis, Structural Characterization, and ReactivityReductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus LigandActivation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand
P50
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P50
name
Jarl Ivar van der Vlugt
@en
type
label
Jarl Ivar van der Vlugt
@en
prefLabel
Jarl Ivar van der Vlugt
@en