Clathrochelate
In coordination chemistry, clathrochelates are ligands that encapsulate metal ions. Chelating ligands bind to metals more strongly than related monodentate ligands, and macrocyclic ligands bind more strongly than typical chelating ligands. It follows, that bi- or polymacrocyclic ligands would bind to metals particularly strongly. Clathrochelates are usually derived from bimacrocyclic ligands. The first examples were derived from the tris(dioximate)s of cobalt(II) and iron(II). The synthesis entails replacement of the hydrogen-bonded proton center with BF2+ or BOR2+ group:
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Clathrochelate
In coordination chemistry, clathrochelates are ligands that encapsulate metal ions. Chelating ligands bind to metals more strongly than related monodentate ligands, and macrocyclic ligands bind more strongly than typical chelating ligands. It follows, that bi- or polymacrocyclic ligands would bind to metals particularly strongly. Clathrochelates are usually derived from bimacrocyclic ligands. The first examples were derived from the tris(dioximate)s of cobalt(II) and iron(II). The synthesis entails replacement of the hydrogen-bonded proton center with BF2+ or BOR2+ group:
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In coordination chemistry, cla ...... e with simpler ligand systems.
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In coordination chemistry, cla ...... nter with BF2+ or BOR2+ group:
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Clathrochelate
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