TEMPO
(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl or (2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl, commonly known as TEMPO, is a chemical compound with the formula (CH2)3(CMe2)2NO. This heterocyclic compound is a red-orange, sublimable solid. As a stable radical, it has applications in chemistry and biochemistry. TEMPO was discovered by Lebedev and Kazarnowskii in 1960. It is prepared by oxidation of 2,2,6,6-tetramethylpiperidine. TEMPO is widely used as a radical marker, as a structural probe for biological systems in conjunction with electron spin resonance spectroscopy, as a reagent in organic synthesis, and as a mediator in controlled radical polymerization. The stability of this radical is attributed to the resonance provided by non-bonding electrons on the nitrogen atom, which form a 2c3e (half
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TEMPO
(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl or (2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl, commonly known as TEMPO, is a chemical compound with the formula (CH2)3(CMe2)2NO. This heterocyclic compound is a red-orange, sublimable solid. As a stable radical, it has applications in chemistry and biochemistry. TEMPO was discovered by Lebedev and Kazarnowskii in 1960. It is prepared by oxidation of 2,2,6,6-tetramethylpiperidine. TEMPO is widely used as a radical marker, as a structural probe for biological systems in conjunction with electron spin resonance spectroscopy, as a reagent in organic synthesis, and as a mediator in controlled radical polymerization. The stability of this radical is attributed to the resonance provided by non-bonding electrons on the nitrogen atom, which form a 2c3e (half
has abstract
(2,2,6,6-Tetramethylpiperidin- ...... eaker than a typical O–H bond.
@en
2,2,6,6-Tetramethylpiperidinyl ...... auer von einer Minute besitzt.
@de
2,2,6,6-四甲基哌啶-1-氧化物（TEMPO）是一种典型的哌啶类氮氧自由基。
@zh
Le (2,2,6,6-tétraméthylpipérid ...... le que la liaison O–H typique.
@fr
TEMPO (систематическое названи ...... ым и Казарновским в 1960 году.
@ru
TEMPO, de afkorting voor 2,2,6 ...... matig oplosbaar zijn in water.
@nl
有機化合物のTEMPO とは、ニトロキシルラジカル (R2N ...... ロースからセルロースナノファイバーを製造することに成功した。
@ja
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(2,2,6,6-Tetramethylpiperidin- ...... atom, which form a 2c3e (half
@en
2,2,6,6-Tetramethylpiperidinyl ...... auer von einer Minute besitzt.
@de
2,2,6,6-四甲基哌啶-1-氧化物（TEMPO）是一种典型的哌啶类氮氧自由基。
@zh
Le (2,2,6,6-tétraméthylpipérid ...... tions radicalaires contrôlées.
@fr
TEMPO (систематическое названи ...... ым и Казарновским в 1960 году.
@ru
TEMPO, de afkorting voor 2,2,6 ...... matig oplosbaar zijn in water.
@nl
有機化合物のTEMPO とは、ニトロキシルラジカル (R2N ...... 亜塩素酸ナトリウムは犠牲試薬、再酸化剤としてはたらいている。
@ja
label
(2,2,6,6-Tétraméthylpipéridin-1-yl)oxy
@fr
2,2,6,6-Tetramethylpiperidinyloxyl
@de
TEMPO
@en
TEMPO
@ja
TEMPO
@nl
TEMPO
@ru
四甲基哌啶氧化物
@zh
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TEMPO
@en