Asymmetric hydrogenation
Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen preferentially to one of two faces of an unsaturated substrate molecule, such as an alkene or ketone. The selectivity derives from the manner that the substrate binds to the chiral catalysts. In jargon, this binding transmits spatial information (what chemists refer to as chirality) from the catalyst to the target, favoring the product as a single enantiomer. This "enzyme-like selectivity" is applied to the synthesis of some commercial pharmaceutical agents and agrochemicals.
Asymmetric hydrogenation(R)-2-Methyl-CBS-oxazaborolidine(S)-iPr-PHOX2-Methylbutanoic acidAlbert Sun-Chi ChanArtificial metalloenzymeAsymmetric catalytic reductionBen FeringaBrice BosnichC2-Symmetric ligandsChiral auxiliaryCyclooctadiene rhodium chloride dimerDIPAMPDehydroamino acidDiphenylethylenediamineDuPhosEnantioselective synthesisHistory of science and technology in JapanIridiumJosiphos ligandsLigandMonsantoNoyori asymmetric hydrogenationOrganic redox reactionOrganorhodium chemistryP-Chiral phosphinePhosphine ligandPhosphinooxazolinesPhospholaneProcess chemistryRutheniumRyōji NoyoriSlayton A. Evans, Jr.TetrahydroquinolineTimeline of MonsantoWilliam Standish Knowles
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Asymmetric hydrogenation
Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen preferentially to one of two faces of an unsaturated substrate molecule, such as an alkene or ketone. The selectivity derives from the manner that the substrate binds to the chiral catalysts. In jargon, this binding transmits spatial information (what chemists refer to as chirality) from the catalyst to the target, favoring the product as a single enantiomer. This "enzyme-like selectivity" is applied to the synthesis of some commercial pharmaceutical agents and agrochemicals.
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Asymmetric hydrogenation is a ...... of N-acetyl dehydroaminoacids
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الهدرجة غير المتماثلة: الهدرجة ...... أشكالها الهندسية غير المنضبطة
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Asymmetric hydrogenation
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هدرجة غير متماثلة
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A chiral monophosphine derived from BINOL
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A chiral monophosphine derived from ferrocene
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The historically important CAMP ligand
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A BINOL derivative
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A ferrocene derivative
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Effective ligand for various asymmetric-hydrogenation processes
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Generic PHOX ligand architecture
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The CAMP ligand
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CAMP.tif
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ChiralMonophosphine.tif
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ChiralMonophosphine2.tif
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Generic PHOX Ligand.tif
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PO Ligand Asymmetric Hydrogenation.tif
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(31.5*3) round 0
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(48.2*3) round 0
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Asymmetric hydrogenation is a ...... ical agents and agrochemicals.
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الهدرجة غير المتماثلة: الهدرجة ...... ة البلاتينية: المعادن الأساسية
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