Aza-Cope rearrangement
Rearrangements, especially those that can participate in cascade reactions, such as the aza-Cope rearrangements, are of high practical as well as conceptual importance in organic chemistry, due to their ability to quickly build structural complexity out of simple starting materials. The aza-Cope rearrangements are examples of heteroatom versions of the Cope rearrangement, which is a [3,3]-sigmatropic rearrangement that shifts single and double bonds between two allylic components. . Aza-Cope rearrangements are generally classified by the position of the nitrogen in the molecule (see figure):
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Aza-Cope rearrangement
Rearrangements, especially those that can participate in cascade reactions, such as the aza-Cope rearrangements, are of high practical as well as conceptual importance in organic chemistry, due to their ability to quickly build structural complexity out of simple starting materials. The aza-Cope rearrangements are examples of heteroatom versions of the Cope rearrangement, which is a [3,3]-sigmatropic rearrangement that shifts single and double bonds between two allylic components. . Aza-Cope rearrangements are generally classified by the position of the nitrogen in the molecule (see figure):
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Rearrangements, especially tho ...... ive research on this reaction.
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Rearrangements, especially tho ...... in the molecule (see figure):
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Aza-Cope rearrangement
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