Ekplexite is a unique sulfide-hydroxide niobium-rich mineral with the formula (Nb,Mo)S2•(Mg1-xAlx)(OH)2+x. It is unique because niobium is usually found in oxide or, eventually, silicate minerals. Ekplexite is a case in which chalcophile behaviour of niobium is shown, which means niobium present in a sulfide mineral. The unique combination of elements in ekplexite has to do with its name, which comes from a Greek world on "surprise". The other example of chalcophile behaviour of niobium is edgarite, FeNb3S6, and both minerals were found in the same environment, which is a fenitic rock of Mt. Kaskasnyunchorr, Khibiny Massif, Kola Peninsula, Russia. Analysis of the same rock has revealed the presence of two analogues of ekplexite, (molybdenum-analogue) and (molybdenum- and manganese-analog