Gold heptafluoride
Gold heptafluoride is a gold(V) compound with the empirical formula AuF7. The synthesis of this compound was first reported in 1986. Current calculations suggest that its structure is actually a difluorine ligand on a gold pentafluoride core, AuF5·F2. That would make it the first difluorine complex and the first compound containing a fluorine atom with an oxidation state of zero. The gold(V)–difluorine complex is calculated to be 205 kJ/mol more stable than gold(VII) fluoride. The vibrational frequency at 734 cm−1 is the hallmark of the end-on coordinated difluorine molecule.
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Gold heptafluoride
Gold heptafluoride is a gold(V) compound with the empirical formula AuF7. The synthesis of this compound was first reported in 1986. Current calculations suggest that its structure is actually a difluorine ligand on a gold pentafluoride core, AuF5·F2. That would make it the first difluorine complex and the first compound containing a fluorine atom with an oxidation state of zero. The gold(V)–difluorine complex is calculated to be 205 kJ/mol more stable than gold(VII) fluoride. The vibrational frequency at 734 cm−1 is the hallmark of the end-on coordinated difluorine molecule.
has abstract
Gold heptafluoride is a gold(V ...... ordinated difluorine molecule.
@en
L'heptafluorure d'or est un co ...... née dans l'heptafluorure d'or.
@fr
七氟化金是一种金的氟化物,化学式为AuF7。这种化合物最早于 ...... 在734cm-1有伸缩振动,也就是端基配位的氟分子键长增大。
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alternative name
Gold heptafluoride
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IUPAC name
Difluorinegold(V) fluoride
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Wikipage page ID
33,788,696
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1,021,760,544
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ImageNameL
Gold heptafluoride
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IUPACName
Difluorinegold fluoride
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name
Gold heptafluoride
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OtherNames
Gold heptafluoride
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verifiedrevid
388,262,175
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comment
Gold heptafluoride is a gold(V ...... ordinated difluorine molecule.
@en
L'heptafluorure d'or est un co ...... née dans l'heptafluorure d'or.
@fr
七氟化金是一种金的氟化物,化学式为AuF7。这种化合物最早于 ...... 在734cm-1有伸缩振动,也就是端基配位的氟分子键长增大。
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label
Gold heptafluoride
@en
Heptafluorure d'or
@fr
七氟化金
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name
Gold heptafluoride
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