Nozaki–Hiyama–Kishi reaction
The Nozaki–Hiyama–Kishi reaction is a nickel/chromium coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide. In their original 1977 publication, Tamejiro Hiyama and Hitoshi Nozaki reported on a chromium(II) salt solution prepared by reduction of chromic chloride by lithium aluminium hydride to which was added benzaldehyde and allyl chloride: In the same year Yoshito Kishi et al. independently discovered the beneficial effects of nickel in his quest for palytoxin: Palladium acetate was also found to be an effective cocatalyst.
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AlcoholAldehydeBarbier reactionChromium(II) chlorideDeaths in September 2019Hitoshi NozakiHiyamaKrische allylationList of organic reactionsNHK (disambiguation)NHK couplingNHK reactionNozaki-Hiyama-Kishi Nickel/Chromium Coupling reactionNozaki-Hiyama-Kishi reactionNozaki-Hiyama reactionOrganochromium chemistryTamejiro HiyamaYoshito Kishi
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Nozaki–Hiyama–Kishi reaction
The Nozaki–Hiyama–Kishi reaction is a nickel/chromium coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide. In their original 1977 publication, Tamejiro Hiyama and Hitoshi Nozaki reported on a chromium(II) salt solution prepared by reduction of chromic chloride by lithium aluminium hydride to which was added benzaldehyde and allyl chloride: In the same year Yoshito Kishi et al. independently discovered the beneficial effects of nickel in his quest for palytoxin: Palladium acetate was also found to be an effective cocatalyst.
has abstract
The Nozaki–Hiyama–Kishi reacti ...... to be an effective cocatalyst.
@en
Η αντίδραση Hiyama είναι οργαν ...... Βικιπαίδεια επεκτείνοντάς το!
@el
野崎-桧山-岸反应(Nozaki-Hiyama-Kishi反 ...... 偶联为醇的反应。该反应的反应形式与Barbier 反应相同。
@zh
野崎・檜山・岸反応(のざき・ひやま・きしはんのう、Nozak ...... のざき・ひやま・きし・たかいはんのう)と呼ばれることもある。
@ja
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1,004,604,408
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name
Nozaki-Hiyama-Kishi reaction
@en
namedafter
type
Coupling reaction
@en
wikiPageUsesTemplate
hypernym
type
comment
The Nozaki–Hiyama–Kishi reacti ...... to be an effective cocatalyst.
@en
Η αντίδραση Hiyama είναι οργαν ...... Βικιπαίδεια επεκτείνοντάς το!
@el
野崎-桧山-岸反应(Nozaki-Hiyama-Kishi反 ...... 偶联为醇的反应。该反应的反应形式与Barbier 反应相同。
@zh
野崎・檜山・岸反応(のざき・ひやま・きしはんのう、Nozak ...... のざき・ひやま・きし・たかいはんのう)と呼ばれることもある。
@ja
label
Nozaki-Hiyama-Kishi-Reaktion
@de
Nozaki–Hiyama–Kishi reaction
@en
Αντίδραση Χιιάμα
@el
野崎–桧山–岸反应
@zh
野崎・檜山・岸反応
@ja