Peroxyoxalate

Peroxyoxalates are esters initially formed by the reaction of hydrogen peroxide with oxalate diesters or oxalyl chloride, with or without base, although the reaction is much faster with base: Peroxyoxalates are intermediates that will rapidly transform into 1,2-dioxetanedione, another high-energy intermediate. The likely mechanism of 1,2-dioxetanedione formation from peroxyoxalate in base is illustrated below: are widely used in analytical chemistry [14, 15]

Peroxyoxalate

Peroxyoxalates are esters initially formed by the reaction of hydrogen peroxide with oxalate diesters or oxalyl chloride, with or without base, although the reaction is much faster with base: Peroxyoxalates are intermediates that will rapidly transform into 1,2-dioxetanedione, another high-energy intermediate. The likely mechanism of 1,2-dioxetanedione formation from peroxyoxalate in base is illustrated below: are widely used in analytical chemistry [14, 15]