Trifluoroperacetic acid
Trifluoroperacetic acid (trifluoroperoxyacetic acid, TFPAA) is an organofluorine compound, the peroxy acid analog of trifluoroacetic acid, with the condensed structural formula CF3COOOH. It is a strong oxidizing agent for organic oxidation reactions, such as in Baeyer–Villiger oxidations of ketones. It is the most reactive of the organic peroxy acids, allowing it to successfully oxidise relatively unreactive alkenes to epoxides where other peroxy acids are ineffective. It can also oxidise the chalcogens in some functional groups, such as by transforming selenoethers to selones. It is a potentially explosive material and is not commercially available, but it can be quickly prepared as needed. Its use as a laboratory reagent was pioneered and developed by William D. Emmons.
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(Bis(trifluoroacetoxy)iodo)benzene1,3-Dichloro-2-nitrobenzeneBaeyer–Villiger oxidationC2HF3O3DioxolaneHexamethylbenzeneMesitylenePeracetic acidPeroxytrifluoroacetic acidReductive dehalogenation of halo ketonesScopineSodium percarbonateSulfenyl chlorideSulfinyl halideTFPAAThiophene1,2-dimethoxyethaanTrifluoroperoxyacetic acidWilliam D. Emmons
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Trifluoroperacetic acid
Trifluoroperacetic acid (trifluoroperoxyacetic acid, TFPAA) is an organofluorine compound, the peroxy acid analog of trifluoroacetic acid, with the condensed structural formula CF3COOOH. It is a strong oxidizing agent for organic oxidation reactions, such as in Baeyer–Villiger oxidations of ketones. It is the most reactive of the organic peroxy acids, allowing it to successfully oxidise relatively unreactive alkenes to epoxides where other peroxy acids are ineffective. It can also oxidise the chalcogens in some functional groups, such as by transforming selenoethers to selones. It is a potentially explosive material and is not commercially available, but it can be quickly prepared as needed. Its use as a laboratory reagent was pioneered and developed by William D. Emmons.
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Trifluoroperacetic acid (trifl ...... eveloped by William D. Emmons.
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alternative name
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Peroxytrifluoroacetic acid
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TFPAA
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Trifluoroethanperoxoic acid
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Trifluoroperacetic acid
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Trifluoroperoxyacetic acid
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IUPAC name
Trifluoroethaneperoxoic acid
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Wikipage page ID
52,821,456
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1,020,097,058
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OtherNames
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Peroxytrifluoroacetic acid
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TFPAA
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Trifluoroethanperoxoic acid
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Trifluoroperacetic acid
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Trifluoroperoxyacetic acid
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PIN
Trifluoroethaneperoxoic acid
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Trifluoroperacetic acid (trifl ...... eveloped by William D. Emmons.
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label
Trifluoroperacetic acid
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