Murrayville is a town on the section of the Mallee Highway between Ouyen and the South Australian border. It is about 24 kilometres (15 mi) east of the South Australian border and 536 kilometres (333 mi) north west of the state capital Melbourne, but 268 kilometres (167 mi) east of Adelaide. At the 2006 census, Murrayville had a population of 444. The local school, Murrayville Community College is a P-12 school.