Agostic interaction
Agostic interaction is a term in organometallic chemistry for the interaction of a coordinatively-unsaturated transition metal with a C−H bond, when the two electrons involved in the C−H bond enter the empty d-orbital of a transition metal, resulting in a three-center two-electron bond. Many catalytic transformations, e.g. oxidative addition and reductive elimination, are proposed to proceed via intermediates featuring agostic interactions. Agostic interactions are observed throughout organometallic chemistry in alkyl, alkylidene, and polyenyl ligands.
18-electron ruleAgosticAgostic complexAgostic compoundAgostic interactionsAnagosticAtoms in moleculesChain walkingCovalent bondDecacarbonyldihydridotriosmiumDichlorotris(triphenylphosphine)ruthenium(II)Dihydrogen complexHapticityHydrocarbon complexKinetic isotope effectKulinkovich reactionLigandLyndon EmsleyMalcolm Green (chemist)Metal hydrocarbon complexMethyllithiumMurai reactionNon-coordinating anionOrganolithium reagentOxidative additionPlumbyleneStannyleneSteven IttelThree-center two-electron bondTransition metal alkyl complexesTransition metal silane complexesTriosmium dodecacarbonyl
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Agostic interaction
Agostic interaction is a term in organometallic chemistry for the interaction of a coordinatively-unsaturated transition metal with a C−H bond, when the two electrons involved in the C−H bond enter the empty d-orbital of a transition metal, resulting in a three-center two-electron bond. Many catalytic transformations, e.g. oxidative addition and reductive elimination, are proposed to proceed via intermediates featuring agostic interactions. Agostic interactions are observed throughout organometallic chemistry in alkyl, alkylidene, and polyenyl ligands.
has abstract
Agostic interaction is a term ...... ylidene, and polyenyl ligands.
@en
Interacció agòstica és la inte ...... del metall, resultant en un .
@ca
Interacción agóstica es un tér ...... ligantes alquilo, y polienilo.
@es
Interaksi agostik merupakan is ...... kil, alkilidena, dan polienil.
@in
Interazione agostica è un term ...... , alchilidenico e polienilico.
@it
Le mot agostique a été introdu ...... llustrée par W(CO)3(PiPr3)2H2.
@fr
Агостична взаємодія (рос. агос ...... границях 1.85 — 2.4 ангстрем.
@uk
التآثر الضام هو مصطلح يستخدم ف ...... ffin لوصف هذا التوع من التآثر.
@ar
アゴスティック相互作用(あごすてぃっくそうごさよう、英;ag ...... を有する有機金属化合物でアゴスティック相互作用が観察される。
@ja
抓氢键(又称agostic键,英語:Agostic interaction)是一种烷基、烯基、炔基或芳基中的氢与过渡金属间形成的3c2e键。
@zh
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Agostic interaction is a term ...... ylidene, and polyenyl ligands.
@en
Interacció agòstica és la inte ...... del metall, resultant en un .
@ca
Interacción agóstica es un tér ...... ligantes alquilo, y polienilo.
@es
Interaksi agostik merupakan is ...... kil, alkilidena, dan polienil.
@in
Interazione agostica è un term ...... , alchilidenico e polienilico.
@it
Le mot agostique a été introdu ...... aîne de polymère en formation.
@fr
Агостична взаємодія (рос. агос ...... томом металу (М) в комплексах.
@uk
التآثر الضام هو مصطلح يستخدم ف ...... روابط تبدي خاصية التآثر الضام.
@ar
アゴスティック相互作用(あごすてぃっくそうごさよう、英;ag ...... を有する有機金属化合物でアゴスティック相互作用が観察される。
@ja
抓氢键(又称agostic键,英語:Agostic interaction)是一种烷基、烯基、炔基或芳基中的氢与过渡金属间形成的3c2e键。
@zh
label
Agostic interaction
@en
Agostische Wechselwirkung
@de
Interacció agòstica
@ca
Interacción agóstica
@es
Interaction agostique
@fr
Interaksi agostik
@in
Interazione agostica
@it
Агостична взаємодія
@uk
تآثر ضام
@ar
アゴスティック相互作用
@ja