Anaïs Napoleón (Anne Tiffon Cassan; 1827 or 1831 in Narbonne, France – 1912 or 1916) was a French-Spanish photographer. She was one of the first women who made daguerreotypes in Spain. She was also a specialist in making business cards that included photographs. Napoleon was always very interested in learning about photographic advances and applied them to her work. Some evidence suggests that she was the only woman working with moving images.