Disiamylborane
Disiamylborane (bis(1,2-dimethylpropyl)borane, Sia2BH) is an organoborane used in organic synthesis. It is used for hydroboration–oxidation reactions of terminal alkynes, giving aldehydes via anti-Markovnikov hydration followed by tautomerization. Disiamylborane is relatively selective for terminal alkynes and alkenes vs internal alkynes and alkenes.. Disiamylborane is prepared by hydroboration of trimethylethylene with diborane. The reaction stops at the secondary borane due to steric hindrance.
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Disiamylborane
Disiamylborane (bis(1,2-dimethylpropyl)borane, Sia2BH) is an organoborane used in organic synthesis. It is used for hydroboration–oxidation reactions of terminal alkynes, giving aldehydes via anti-Markovnikov hydration followed by tautomerization. Disiamylborane is relatively selective for terminal alkynes and alkenes vs internal alkynes and alkenes.. Disiamylborane is prepared by hydroboration of trimethylethylene with diborane. The reaction stops at the secondary borane due to steric hindrance.
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Bis(1,2-dimethylpropyl)boraan, ...... met als brutoformule C10H23B.
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Disiamylborane (bis(1,2-dimeth ...... orane due to steric hindrance.
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Дисиамилборан (бис-(1,2-димети ...... енение в органическом синтезе.
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IUPAC name
Bis(1,2-dimethylpropyl)borane
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17,504,215
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934,064,391
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Ball-and-stick model of the disiamylborane molecule
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Skeletal formula of disiamylborane
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Bisborane
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399,911,516
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Bis(1,2-dimethylpropyl)boraan, ...... met als brutoformule C10H23B.
@nl
Disiamylborane (bis(1,2-dimeth ...... orane due to steric hindrance.
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Дисиамилборан (бис-(1,2-димети ...... енение в органическом синтезе.
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label
Bis(1,2-dimethylpropyl)boraan
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Disiamylborane
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Дисиамилборан
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