Lindgren oxidation
Lindgren oxidation is a selective method for oxidizing aldehydes to carboxylic acids. The reaction is named after Bengt O. Lindgren. The oxidation takes place in water containing solvent mixtures under slightly acidic conditions (pH 3–5) with sodium chlorite as oxidizer. To avoid complicated oxidation reactions the hypochlorite, which is formed in the reaction, has to be removed from the reaction mixture by scavengers. In the original publication, sulfamic acid and resorcinol were used. George A. Kraus and co-workers were the first to use 2-methyl-2-butene as scavenger under buffered conditions for the oxidation of an aliphatic and an α,β-unsaturated aldehyde. Later hydrogen peroxide also proved to work to remove the hypochlorite.
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Lindgren oxidation
Lindgren oxidation is a selective method for oxidizing aldehydes to carboxylic acids. The reaction is named after Bengt O. Lindgren. The oxidation takes place in water containing solvent mixtures under slightly acidic conditions (pH 3–5) with sodium chlorite as oxidizer. To avoid complicated oxidation reactions the hypochlorite, which is formed in the reaction, has to be removed from the reaction mixture by scavengers. In the original publication, sulfamic acid and resorcinol were used. George A. Kraus and co-workers were the first to use 2-methyl-2-butene as scavenger under buffered conditions for the oxidation of an aliphatic and an α,β-unsaturated aldehyde. Later hydrogen peroxide also proved to work to remove the hypochlorite.
has abstract
Lindgren oxidation is a select ...... rk to remove the hypochlorite.
@en
Lindgren氧化反应(Lindgren oxidatio ...... 以使用氨基磺酸-间苯二酚或双氧水作为去除次氯酸根离子的试剂。
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name
Lindgren oxidation
@en
namedafter
Bengt O. Lindgren
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type
Organic redox reaction
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wikiPageUsesTemplate
hypernym
type
comment
Lindgren oxidation is a select ...... rk to remove the hypochlorite.
@en
Lindgren氧化反应(Lindgren oxidatio ...... 以使用氨基磺酸-间苯二酚或双氧水作为去除次氯酸根离子的试剂。
@zh
label
Lindgren oxidation
@en
林德格伦氧化反应
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