Octaoxygen

Octaoxygen is an allotrope of oxygen consisting of eight oxygen atoms. As the pressure of oxygen at room temperature is increased through 10 gigapascals (1,500,000 psi), it undergoes a dramatic phase transition to a different allotrope. Its volume decreases significantly, and it changes color from sky-blue to deep red. This ε-phase was discovered in 1979, but the structure has been unclear. Based on infrared spectroscopy, researchers assumed in 1999 that this phase consists of O4 molecules in a crystal lattice. However, in 2006, it was shown by X-ray crystallography that this stable phase known as ε oxygen or red oxygen is in fact O8. No one predicted the structure theoretically: a rhomboid O8 cluster consisting of four O2 molecules.

Octaoxygen

Octaoxygen is an allotrope of oxygen consisting of eight oxygen atoms. As the pressure of oxygen at room temperature is increased through 10 gigapascals (1,500,000 psi), it undergoes a dramatic phase transition to a different allotrope. Its volume decreases significantly, and it changes color from sky-blue to deep red. This ε-phase was discovered in 1979, but the structure has been unclear. Based on infrared spectroscopy, researchers assumed in 1999 that this phase consists of O4 molecules in a crystal lattice. However, in 2006, it was shown by X-ray crystallography that this stable phase known as ε oxygen or red oxygen is in fact O8. No one predicted the structure theoretically: a rhomboid O8 cluster consisting of four O2 molecules.