Sharpless asymmetric dihydroxylation
Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence of a chiral quinine ligand to form a vicinal diol. The reaction has been applied to alkenes of virtually every substitution, often high enantioselectivities are realized. Asymmetric dihydroxylation reactions are also highly site selective, providing products derived from reaction of the most electron-rich double bond in the substrate.
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(E)-Stilbene20th century in scienceAD-mixAD (disambiguation)AlkeneAsymmetric catalytic oxidationAsymmetric dihydroxylationC2-Symmetric ligandsCatalytic oxidationDihydroquinidineDihydroquinineDihydroxylationDiolEnantioselective synthesisHistory of chemistryHomogeneous catalysisHydroxylationKarl Barry SharplessKinetic resolutionKuwajima Taxol total synthesisLemieux–Johnson oxidationList of Nobel laureates in ChemistryList of organic reactionsLurtotecanMilas hydroxylationN-Methylmorpholine N-oxideOsmiumOsmium tetroxidePotassium ferricyanidePotassium osmateQuinidineQuinineRubottom oxidationSharplessSharpless DihydroxylationSharpless bishydroxylationSharpless dihydroxylationSharpless oxyaminationStereoselectivityTimeline of chemistry
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Sharpless asymmetric dihydroxylation
Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence of a chiral quinine ligand to form a vicinal diol. The reaction has been applied to alkenes of virtually every substitution, often high enantioselectivities are realized. Asymmetric dihydroxylation reactions are also highly site selective, providing products derived from reaction of the most electron-rich double bond in the substrate.
has abstract
A di-hidroxilação assimétrica ...... l para formar um diol vicinal.
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Asymetryczna dihydroksylacja S ...... odę Nobla w dziedzinie chemii.
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Die Asymmetrische Dihydroxylie ...... es chiralen Liganden zustande.
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Dihidroksilasi asimetris Sharp ...... h Nobel Kimia pada tahun 2001.
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La dihidroxilación asimétrica ...... )2-PHAL se denomina AD-mix-β.
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La diidrossilazione asimmetric ...... i due enantiomeri del ligando.
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Sharpless asymmetric dihydroxy ...... 2001 Nobel Prize in Chemistry.
@en
Асимметричное дигидроксилирова ...... лизируемых реакций окисления».
@ru
シャープレス不斉ジヒドロキシ化（しゃーぷれすふせいひどろきし ...... を共存させることで光学活性なジオールを得る手法のことである。
@ja
夏普莱斯不对称双羟基化反应（Sharpless asymme ...... 生物 (DHQ)2-PHAL 和 (DHQD)2-PHAL。
@zh
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name
Sharpless asymmetric dihydroxylation
@en
namedafter
type
Addition reaction
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hypernym
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A di-hidroxilação assimétrica ...... l para formar um diol vicinal.
@pt
Asymetryczna dihydroksylacja S ...... (DHQD)2-PHAL jest to AD-mix-β.
@pl
Die Asymmetrische Dihydroxylie ...... es chiralen Liganden zustande.
@de
Dihidroksilasi asimetris Sharp ...... (DHQD)2-PHAL disebut AD-mix-β.
@in
La dihidroxilación asimétrica ...... ara formar un diol vecinal.
@es
La diidrossilazione asimmetric ...... iducendo l'impatto ambientale.
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Sharpless asymmetric dihydroxy ...... double bond in the substrate.
@en
Асимметричное дигидроксилирова ...... высокой стереоселективностью.
@ru
シャープレス不斉ジヒドロキシ化（しゃーぷれすふせいひどろきし ...... を共存させることで光学活性なジオールを得る手法のことである。
@ja
夏普莱斯不对称双羟基化反应（Sharpless asymme ...... 生物 (DHQ)2-PHAL 和 (DHQD)2-PHAL。
@zh
label
Asymetryczna dihydroksylacja Sharplessa
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Asymmetrische Dihydroxylierung
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Di-hidroxilação assimétrica de Sharpless
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Dihidroksilasi asimetris Sharpless
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Dihidroxilación asimétrica de Sharpless
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Diidrossilazione asimmetrica di Sharpless
@it
Sharpless asymmetric dihydroxylation
@en
Асимметричное дигидроксилирование по Шарплессу
@ru
シャープレス不斉ジヒドロキシ化
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夏普莱斯不对称双羟基化反应
@zh