Tsuji–Trost reaction
The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.
known for
AAAAllyl groupAllylic asymmetric alkylationAllylic asymmetric substitutionAsymmetric allylic alkylationBarry TrostBrian StoltzDecarboxylationGalantamine total synthesisList of organic reactionsOrganopalladiumPalladiumPhosphinooxazolinesSpirotryprostatin BStrychnine total synthesisTris(dibenzylideneacetone)dipalladium(0)TrostTrost AAA reactionTrost asymmetric allylic alkylationTrost ligandTsujiTsuji-TrostTsuji-Trost reactionTsuji Trost reactionVinylcyclopropane (5+2) cycloaddition
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Tsuji–Trost reaction
The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.
has abstract
Die Tsuji-Trost-Reaktion oder ...... Tsuji und Barry Trost benannt.
@de
La reacción Tsuji–Trost (tambi ...... ntesis de productos naturales.
@es
The Tsuji–Trost reaction (also ...... and natural product synthesis.
@en
Η αντίδραση Τσούζι-Τροστ είναι ...... (dba)3.CHCl3, Pd(OCOCH3)2+PPh3
@el
Алілювання за Тростом (англ. T ...... іла та замісників у субстраті.
@uk
辻-特罗斯特反应是以鈀為催化劑、親核取代反應物种的烯丙基化反应。親核物種可能是醇、烯醇、苯酚或烯胺。離去基可以是鹵素或乙醯氧基。
@zh
辻・トロスト反応(つじトロストはんのう、英: Tsuji-T ...... ンが反応の進行に必要である(辻の条件では反応は進行しない)。
@ja
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Die Tsuji-Trost-Reaktion oder ...... Tsuji und Barry Trost benannt.
@de
La reacción Tsuji–Trost (tambi ...... ltado el producto sustituido.
@es
The Tsuji–Trost reaction (also ...... ng in the substituted product.
@en
Η αντίδραση Τσούζι-Τροστ είναι ...... (dba)3.CHCl3, Pd(OCOCH3)2+PPh3
@el
Алілювання за Тростом (англ. T ...... іла та замісників у субстраті.
@uk
辻-特罗斯特反应是以鈀為催化劑、親核取代反應物种的烯丙基化反应。親核物種可能是醇、烯醇、苯酚或烯胺。離去基可以是鹵素或乙醯氧基。
@zh
辻・トロスト反応(つじトロストはんのう、英: Tsuji-T ...... ンが反応の進行に必要である(辻の条件では反応は進行しない)。
@ja
label
Reacción Tsuji–Trost
@es
Tsuji-Trost-Reaktion
@de
Tsuji–Trost reaction
@en
Αντίδραση Τσούζι-Τροστ
@el
Алілювання за Тростом
@uk
辻-特罗斯特反应
@zh
辻・トロスト反応
@ja