Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
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Cation-pi control of regiochemistry of intramolecular schmidt reactions en route to bridged bicyclic lactamsTotal Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF3 ComplexStability of medium-bridged twisted amides in aqueous solutions.Naturally diverse: highlights in versatile synthetic methods enabling target- and diversity-oriented synthesis.Proximity effects in nucleophilic addition reactions to medium-bridged twisted lactams: remarkably stable tetrahedral intermediates.Synthesis of medium-bridged twisted lactams via cation-pi control of the regiochemistry of the intramolecular Schmidt reaction.Synthesis, structural analysis, and reactivity of bridged orthoamides by intramolecular Schmidt reactionNovel tetracyclic structures from the synthesis of thiolactone-isatin hybridsStructural characterization of N-protonated amides: regioselective N-activation of medium-bridged twisted lactamsChemistry of bridged lactams and related heterocyclesThe stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization.Evolution of a unified, stereodivergent approach to the synthesis of communesin F and perophoramidine.Twisted amide electrophiles enable cyclic peptide sequencing.Radical aryl migration enables diversity-oriented synthesis of structurally diverse medium/macro- or bridged-rings.Origins of regio- and stereochemistry in type 2 intramolecular N-acylnitroso Diels-Alder reactions: a computational study of tether length and substituent effects.Direct synthesis of medium-bridged twisted amides via a transannular cyclization strategyCorey-Chaykovsky epoxidation of twisted amides: synthesis and reactivity of bridged spiro-epoxyamines.Electrospray ionization (ESI) fragmentations and dimethyldioxirane reactivities of three diverse lactams having full, half, and zero resonance energies.Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups.Cross-coupling of aromatic esters and amides.Structures of Highly Twisted Amides Relevant to Amide N-C Cross-Coupling: Evidence for Ground-State Amide Destabilization.A modular reaction pairing approach to the diversity-oriented synthesis of fused- and bridged-polycyclic sultams.Pyramidalization/twisting of the amide functional group via remote steric congestion triggered by metal coordination.Uncovering the importance of proton donors in TmI2-promoted electron transfer: facile C-N bond cleavage in unactivated amides.An efficient computational model to predict protonation at the amide nitrogen and reactivity along the C-N rotational pathway.Unexpected reactivity and mechanism of carboxamide activation in bacterial N-linked protein glycosylation.Synthesis of cyclic peptides through an intramolecular amide bond rearrangement.Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids.Experimental and computational studies of anti-Bredt amidinium salts.Nickel-catalyzed transamidation of aliphatic amide derivatives.Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A.Strain-Induced Reactivity in the Dynamic Covalent Chemistry of Macrocyclic Imines.Twisting the ethano-Tröger's base: the bisamide.Stereoselective and Enantiospecific Mono- and Bis-C-H Azidation of Tröger Bases: Insight on Bridgehead Iminium Intermediates and Application to Anion-Binding Catalysis.Access to divergent benzo-heterocycles via a catalyst-dependent strategy in the controllable cyclization of o-alkynyl-N-methoxyl-benzamides.Palladium-catalyzed Suzuki-Miyaura coupling of amides by carbon-nitrogen cleavage: general strategy for amide N-C bond activation.Oxidative amide synthesis directly from alcohols with amines.Direct room-temperature lactonisation of alcohols and ethers onto amides: an "amide strategy" for synthesis.Sterically-controlled intermolecular Friedel-Crafts acylation with twisted amides via selective N-C cleavage under mild conditions.Structural Characterization of N-Alkylated Twisted Amides: Consequences for Amide Bond Resonance and N-C Cleavage.
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P2860
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
description
2006 nî lūn-bûn
@nan
2006 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
name
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@ast
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@en
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@nl
type
label
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@ast
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@en
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@nl
prefLabel
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@ast
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@en
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@nl
P2860
P356
P1433
P1476
Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
@en
P2093
Brian M Stoltz
Kousuke Tani
P2860
P2888
P356
10.1038/NATURE04842
P407
P577
2006-06-08T00:00:00Z
P5875
P6179
1032034038