about
Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic propertiesCyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the LaboratoryAnionic N-heterocyclic carbenes with N,N'-bis(fluoroaryl) and N,N'-bis(perfluoroaryl) substituents.Organic electron donors as powerful single-electron reducing agents in organic synthesis.Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.Stable four-pi-electron, four-membered heterocyclic cations and carbenes.Hybrid super electron donors - preparation and reactivityNHC-Based Self-Assembled Monolayers on Solid Gold Substrates.Tuning the nucleophilicity in cyclopropenylidenes.Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation).One-carbon extrusion from a tetraazafulvalene. Isolation of aldehydes and a study of their origin.Stable cyclic carbenes and related species beyond diaminocarbenes.N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis.Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal ComplexesNew synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines.A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexesStable P-heterocyclic carbenes: scope and limitations.Discovery and development of organic super-electron-donors.Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes.A simple route to phosphamethine cyanines from S,N-heterocyclic carbenes.A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic ActivityA New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds.A persistent P,N-heterocyclic carbene.A Brief Survey of our Contribution to Stable Carbene Chemistry.Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds.Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).A persistent (amino)(ferrocenyl)carbene().A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicityToward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts.A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed CarbamoylboraneImidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts.Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives.Resolution of the atropochiral biminap ligand and applications in asymmetric catalysis.Carbonylation of the simplest persistent diaminocarbene.Temporary intramolecular generation of pyridine carbenes in metal-free three-component C-H bond functionalisation/aryl-transfer reactions.Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: B-H Bond Activation versus Carbene Dimerization.NHC-CAAC Heterodimers with Three Stable Oxidation States.A novel neutral organic electron donor with record half-wave potential.
P2860
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P2860
description
2004 nî lūn-bûn
@nan
2004 թուականի Նոյեմբերին հրատարակուած գիտական յօդուած
@hyw
2004 թվականի նոյեմբերին հրատարակված գիտական հոդված
@hy
2004年の論文
@ja
2004年論文
@yue
2004年論文
@zh-hant
2004年論文
@zh-hk
2004年論文
@zh-mo
2004年論文
@zh-tw
2004年论文
@wuu
name
When and how do diaminocarbenes dimerize?
@ast
When and how do diaminocarbenes dimerize?
@en
When and how do diaminocarbenes dimerize?
@nl
type
label
When and how do diaminocarbenes dimerize?
@ast
When and how do diaminocarbenes dimerize?
@en
When and how do diaminocarbenes dimerize?
@nl
prefLabel
When and how do diaminocarbenes dimerize?
@ast
When and how do diaminocarbenes dimerize?
@en
When and how do diaminocarbenes dimerize?
@nl
P2093
P2860
P356
P1476
When and how do diaminocarbenes dimerize?
@en
P2093
François Paolini
Jan Schütz
Leila Chaker
Michael E Blake
Roger W Alder
P2860
P304
P356
10.1002/ANIE.200400654
P407
P577
2004-11-12T00:00:00Z