about
Low-valent organometallics--synthesis, reactivity, and potential applicationsOxidative addition of water and methanol to a dicationic trivalent phosphorus centre.Preparation and use of carbonyl-decorated carbenes in the activation of white phosphorusCarbene-Stabilized Main Group Radicals and Radical IonsN-Heterocyclic carbene adducts of the heavier group 15 tribromides. Normal to abnormal isomerism and bromide ion abstraction.An Electrophilic Carbene-Anchored Silylene-Phosphinidene.Applications of N-heterocyclic imines in main group chemistry.Design, Synthesis, and Structural Analysis of Divalent N(I) Compounds and Identification of a New Electron-Donating Ligand.A soluble molecular variant of the semiconducting silicondiselenide.Generation of 1,2-azaboretidines via reduction of ADC borane adducts.Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.Stable singlet carbenes as mimics for transition metal centers.N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P-P bond and its subsequent reactivity.A Brief Survey of our Contribution to Stable Carbene Chemistry.Synthesis of a room-temperature-stable dimeric copper(I) hydride.Imidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts.First dinuclear copper/gallium complexes: supporting Cu0 and Cu(I) centres by low-valent organogallium ligands.Group 13 ligand supported heavy-metal complexes: first structural evidence for gallium-lead and gallium-mercury bonds.Diazabutadiene complexes of selenium as Se2+ transfer reagents.The first bismuth-NHC complexes.Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.Isolation of a neutral P8 cluster by [2+2] cycloaddition of a diphosphene facilitated by carbene activation of white phosphorus.Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*).Dative bonds in main-group compounds: a case for fewer arrows!Low-valent Ge(2) and Ge(4) species trapped by N-heterocyclic gallylene.Preparation and Characterization of P2 BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes.A modular approach to carbene-stabilized diphosphorus species.Dinitrogen as double Lewis acid: structure and bonding of triphenylphosphinazine N2(PPh3)2.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Reaction of Pentelidene Complexes with Diazoalkanes: Stabilization of Parent 2,3-Dipnictabutadienes.Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species.The fate of NHC-stabilized dicarbon.Silavinylidene stabilized by an N-heterocyclic carbene: a theoretically predicted stable molecule.Iron(II) complexes of ditopic carbanionic carbenes.Theoretical Evidence for the Utilization of Low-Valent Main-Group Complexes as Rare-Synthon Equivalents.Ligand-Supported E3 Clusters (E=Si-Sn).Bonding in Heavier Group 14 Zero-Valent Complexes-A Combined Maximum Probability Domain and Valence Bond Theory Approach.NHC adducts of tantalum amidohalides: the first example of NHC abnormally coordinated to an early transition metal.A Sixteen-Membered Au8 P8 Macrocycle Based on Gold(I) and Diphospha(III)guanidine.Two Structurally Characterized Conformational Isomers with Different C-P Bonds.
P2860
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P2860
description
2008 nî lūn-bûn
@nan
2008 թուականի Նոյեմբերին հրատարակուած գիտական յօդուած
@hyw
2008 թվականի նոյեմբերին հրատարակված գիտական հոդված
@hy
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
name
Carbene-stabilized diphosphorus
@ast
Carbene-stabilized diphosphorus
@en
Carbene-stabilized diphosphorus
@nl
type
label
Carbene-stabilized diphosphorus
@ast
Carbene-stabilized diphosphorus
@en
Carbene-stabilized diphosphorus
@nl
prefLabel
Carbene-stabilized diphosphorus
@ast
Carbene-stabilized diphosphorus
@en
Carbene-stabilized diphosphorus
@nl
P2093
P356
P1476
Carbene-stabilized diphosphorus
@en
P2093
Gregory H Robinson
Henry F Schaefer
Paul v R Schleyer
Pingrong Wei
R Bruce King
Yaoming Xie
P304
14970-14971
P356
10.1021/JA807828T
P407
P50
P577
2008-10-21T00:00:00Z