Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
about
Chemoselectivity and the curious reactivity preferences of functional groups.Regio- and chemoselective metalation of arenes and heteroarenes using hindered metal amide bases.Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexationSelective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives.Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates.Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture.New insights into addition reactions of dialkylzinc reagents to trifluoromethyl ketones: structural authentication of a beta-hydride elimination product containing a tetranuclear zinc chain.cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation.Characterization of a multicomponent lithium lithiate from a combined x-ray diffraction, NMR spectroscopy, and computational approach.Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.Robert Mulvey.Access to the meta position of arenes through transition metal catalysed C-H bond functionalisation: a focus on metals other than palladium.Functionalization of quinoxalines by using TMP bases: preparation of tetracyclic heterocycles with high photoluminescene quantum yields.An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry.Amido analogues of zincocenes and cadmocenes.Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(i) complex with a NHC anionCharakterisierung eines Mehrkomponenten-Lithiumlithats durch eine Kombination von Röntgenstrukturanalyse, NMR-Spektroskopie und theoretischen StudienHeterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complexPre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formationAfter-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne productsSingle electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalconeNeutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligandsStructural variations in bimetallic sodium–magnesium and sodium–zinc ketimides, and a sodium–zinc alkide–alkoxide–amide: connections to ring-stacking, ring-laddering, and inverse crown concepts
P2860
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P2860
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
description
2006 nî lūn-bûn
@nan
2006 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
name
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
@ast
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
@en
type
label
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
@ast
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
@en
prefLabel
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
@ast
Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation
@en
P2093
P50
P356
P1476
Directed meta-metalation using alkali-metal-mediated zincation
@en
P2093
David R Armstrong
Gordon W Honeyman
Lorna M Hogg
Sophie H Dale
P304
P356
10.1002/ANIE.200600720
P407
P577
2006-06-01T00:00:00Z