Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
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Systematic assembly of the double molecular boxes: [Cs subset [CpCo(CN)(3)](4)[Cp*Ru](3)] as a tridentate ligandHighly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)3](-) (R = NO2, CF3, Cl, F, H, OMe and NMe2) and their copper(I) complexes.A family of four-coordinate iron(II) complexes bearing the sterically hindered tris(pyrazolyl)borato ligand Tp(tBu,Me).Chlorido(1H-imidazole-κN)bis-(triphenyl-phosphane-κP)copper(I).Chloridotris(3,5-dimethyl-1H-pyrazole-κN)(formato-κO)copper(II)-dichlorido-bis(3,5-dimethyl-1H-pyrazole-κN)copper(II) (2/1).2-[(3,5-Diphenyl-1H-pyrazol-1-yl)meth-yl]pyridine.Multidentate 2-pyridyl-phosphine ligands - towards ligand tuning and chirality.Main group pyridyl-based ligands; strategies to mixed metal complexes.Polyimido sulfur anions and ylides.New insights on cytotoxic activity of group 3 and lanthanide compounds: complexes with [N,N,N]-scorpionate ligands.Bis{μ-[(di-phenyl-phosphor-yl)meth-yl](phen-yl)bis-(1H-pyrazol-1-yl)boranuido}dilithiumA new hybrid scorpionate ligand: a study of the metal-boron bond within metallaboratrane complexes.Luminescent Fluorene-Based Bis-Pyrazolyl Aniline Ligand for Aluminum Detection.The versatile behaviour of a novel Janus scorpionate ligand towards sodium, potassium and bismuth(III) ions.Rhodium/iridium-titanium azaheterometallocubanes.Step-by-step uncoordination of the pyrazolyl rings of hydrotris(pyrazolyl)borate ligands in comlexes of Rh and RhIII.Thallium(I) complexes of fluorinated bis- and tris(pyrazolyl)borate ligands: [H2B{3,5-(CF3)2pz}2]Tl and [HB{3,5-(CF3)2pz}3]Tl.Synthesis and characterization of coordinatively unsaturated nickel(II) and manganese(II) alkyl complexes supported by the hydrotris(3-phenyl-5-methylpyrazolyl)borate (Tp(Ph,Me)) ligand.Preparation of mononuclear and dinuclear Rh hydrotris(pyrazolyl)borato complexes containing arenethiolato ligands and conversion of the mononuclear complexes into dinuclear Rh-Rh and Rh-Ir complexes with bridging arenethiolato ligands.Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions.The co-ordination chemistry of tris(3,5-dimethylpyrazolyl)methane manganese carbonyl complexes: synthetic, electrochemical and DFT studies.Highly selective epoxidation of styrene using a transition metal-aluminium(III) complex containing the [MeAl(2-py)3]- anion (2-py = 2-pyridyl).Metal and ligand substitution of the aluminium tris-pyridyl ligands [RAl(2-py')(3)](-) (R = Et, (n)Bu, (s)Bu, (t)Bu; 2-py' = 2-pyridyl, 3-methyl-2-pyridyl, 5-methyl-2-pyridyl, 6-methyl-2-pyridyl).Homoleptic 'sandwich' complexes of substituted tris(methimazolyl)borate ligands with ruthenium, rhodium and palladium.A brief history of scorpionates.Sodium, magnesium and zinc complexes of mono(phenolate) heteroscorpionate ligands.X-ray Single Crystal Structure, DFT Calculations and Biological Activity of 2-(3-Methyl-5-(pyridin-2'-yl)-1H-pyrazol-1-yl) Ethanol.An iron(II) complex tripodally chelated with 1,1,1-tris(pyridin-2-yl)ethane showing room-temperature spin-crossover behaviour.Steric and electronic effects on arylthiolate coordination in the pseudotetrahedral complexes [(Tp(Ph,Me))Ni-SAr] (Tp(Ph,Me) = hydrotris{3-phenyl-5-methyl-1-pyrazolyl}borate).The first scorpionate ligand based on diazaphosphole.Scorpionate-type coordination in MFU-4l metal-organic frameworks: small-molecule binding and activation upon the thermally activated formation of open metal sites.Cyclic gas-phase heterogeneous process in a metal-organic framework involving a nickel nitrosyl complex.Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands.Molecular Switches for any pH: A Systematic Study of the Versatile Coordination Behaviour of Cyclam Scorpionands.Synthesis and reactivity of an anionic allenylidene complex.A Boron-Fluorinated Tris(pyrazolyl)borate Ligand ((F) Tp*) and Its Mono- and Dinuclear Copper Complexes [Cu((F) Tp*)2 ] and [Cu2 ((F) Tp*)2 ]: Synthesis, Structures, and DFT Calculations.Steric and electronic factor comparisons in hydrotris(3-phenylpyrazolyl)borate nickel(II) aryloxides.[3 + 2] cycloaddition and subsequent oxidative dehydrogenation between alkenes and diazo compounds: a simple and direct approach to pyrazoles using TBAI/TBHP.Structure and photoluminescence of silver(i) trinuclear halopyrazolato complexes.Variable coordination geometries via an amine-tethered-enamidophosphinimine ligand on cobalt.
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P2860
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
description
1993 թուականի Մայիսին հրատարակուած գիտական յօդուած
@hyw
1993 թվականի մայիսին հրատարակված գիտական հոդված
@hy
artículu científicu espublizáu en 1993
@ast
im Mai 1993 veröffentlichter wissenschaftlicher Artikel
@de
scientific article (publication date: May 1993)
@en
wetenschappelijk artikel (gepubliceerd in 1993-05)
@nl
наукова стаття, опублікована в травні 1993
@uk
مقالة علمية (نشرت في مايو 1993)
@ar
name
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@ast
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@en
type
label
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@ast
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@en
prefLabel
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@ast
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@en
P356
P1433
P1476
Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
@en
P2093
S. Trofimenko
P304
P356
10.1021/CR00019A006
P577
1993-05-01T00:00:00Z