(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent

(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent

Item
http://www.wikidata.org/entity/Q29039551
Stable cyclic carbenes and related species beyond diaminocarbenes.New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines.Borylenes: An Emerging Class of Compounds.Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes.Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes.Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts.Intramolecular hydroxycarbene C-H-insertion: The curious case of (o-methoxyphenyl)hydroxycarbene.A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic ActivityA Brief Survey of our Contribution to Stable Carbene Chemistry.Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds.A persistent (amino)(ferrocenyl)carbene().Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts.An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene.Activation of C-F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexes.N,N'-diamidocarbenes facilitate selective C-H insertions and transfer hydrogenations.
P2860

(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent

Item
http://www.wikidata.org/entity/Q29039551
description
2001 nî lūn-bûn
@nan
2001 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2001 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2001年の論文
@ja
2001年論文
@yue
2001年論文
@zh-hant
2001年論文
@zh-hk
2001年論文
@zh-mo
2001年論文
@zh-tw
2001年论文
@wuu
name
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@ast
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@en
type
label
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@ast
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@en
prefLabel
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@ast
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@en
P1433
P1476
P2093
P304
P31
P356
P407
P433
P478
P577
P698
P356
P1433
P1476
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
@en
P2093
P304
P31
P356
10.1126/SCIENCE.292.5523.1901
P407
P433
P478
P577
P698