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A stable aminyl radical metal complexHeteroatom stabilized carbenium ionsThermodynamic and kinetic data for adduct formation, cis-trans isomerization and redox reactions of ML4 complexes: a case study with rhodium- and iridium-tropp complexes in d8, d9 and d10 valence electron configurations (tropp=dibenzotropylidene phoCyclo-oligomerization of isocyanates with Na(PH2) or Na(OCP) as "P-" anion sources.Rhodium(0) metalloradicals in binuclear C-H activation.Electromeric rhodium radical complexes.Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate.A Stable Aminyl Radical Coordinated to Cobalt.From 0 to II in One-Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2.Synthesis, structure, and reactivity of a stabilized phosphiranylium salt.Chemoselective methoxycarbonylation of terminal alkynes catalyzed by Pd(II)-TROPP complexes.Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes.Ru(II)-hydride-trop complexes: X-ray single-crystal determination and quantum-chemical calculations.Tropad: a new ligand for the synthesis of water-stable paramagnetic [16+1]-electron rhodium and iridium complexes.Synthesis and structure of [Na11(OtBu)10(OH)]: 1H NMR shift of a hydroxide ion encapsulated in a 21-vertex alcoholate cage.Olefins as steering ligands for homogeneously catalyzed hydrogenations.Alkylating agents stronger than alkyl triflates.Amine olefin rhodium(I) complexes: pKa and NH bond strength.High-resolution EPR spectroscopic investigations of a homologous set of d9-cobalt(0), d9-rhodium(0), and d9-iridium(0) complexes.Trends in the Periodic System: the mass spectrum of dimethylphenyl phosphane and a comparison of the gas phase reactivity of dimethylphenyl pnictogene radical cations C(6)H(5)E(CH(3))(2)(*+), (E = N, P, As)(dagger).L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes.(L)2 C2 P2 : Dicarbondiphosphide Stabilized by N-Heterocyclic Carbenes or Cyclic Diamido Carbenes.Probing Phosphorus Nitride (P≡N) and Other Elusive Species Formed upon Pyrolysis of Dimethyl Phosphoramidate.Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution.Trends in the reactions of gaseous phenyl pnictogen radical cations C6H5EH2*+ (E = N, P, As).Insights into metal-ligand hydrogen transfer: a square-planar ruthenate complex supported by a tetradentate amino-amido-diolefin ligand.From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene.Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols.A Low-Valent Iron Imido Heterocubane Cluster: Reversible Electron Transfer and Catalysis of Selective C-C Couplings.Reactivity of an All-Ferrous Iron-Nitrogen Heterocubane under Reductive and Oxidative Conditions.Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amides.Elucidating the thermal decomposition of dimethyl methylphosphonate by vacuum ultraviolet (VUV) photoionization: pathways to the PO radical, a key species in flame-retardant mechanisms.A homogeneous transition metal complex for clean hydrogen production from methanol-water mixtures.Sodium compounds of the benzophenone dianion (diphenyloxidomethanide).Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes.Snowballing radical generation leads to ultrahigh molecular weight polymers.Star-shaped Polymers through Simple Wavelength-Selective Free-Radical Photopolymerization.Borane-Stabilized Isomeric Dimers of the Phosphaethynolate Anion.A Convenient Synthesis of 1,2,4- and 1,3,4-Azadiphospholes.2,4,6-Tri(hydroxy)-1,3,5-triphosphinine, P3 C3 (OH)3 : The Phosphorus Analogue of Cyanuric Acid.
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description
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german researcher
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研究者
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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type
label
Hansjörg Grützmacher
@ast
Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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prefLabel
Hansjörg Grützmacher
@ast
Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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Hansjörg Grützmacher
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P214
P227
P108
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7006612159
P21
P214
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1089225008
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0000-0002-1531-8906
P569
1959-01-01T00:00:00Z
P734
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lccn-nb2001029311