Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate.
about
A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups.Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper-nitrene complexes.Alkali metal control over N-N cleavage in iron complexes.Spectroscopic capture and reactivity of a low-spin cobalt(IV)-oxo complex stabilized by binding redox-inactive metal ions.Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺.Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes.New amination strategies based on nitrogen-centered radical chemistry.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Experimental and Theoretical Investigations of the Existence of Cu(II), Cu(III), and Cu(IV) in Copper Corrolato Complexes.Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and BenzenesAlkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides.Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactionsCharacterization and Reactivity Studies of a Terminal Copper-Nitrene Species.A change in the oxidation state of iron: scandium is not innocent.Copper-catalyzed annulation of amidines for quinazoline synthesis.Spin states: discussion of an open problem.Elusive Terminal Copper Arylnitrene Intermediates.Computational exploration of the mechanism of copper-catalyzed aromatic C-H bond amination of benzene via a nitrene insertion approach.A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions.Comparison of the reactivity of nonheme iron(IV)-oxo versus iron(IV)-imido complexes: which is the better oxidant?An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state.Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species
P2860
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P2860
Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate.
description
2012 nî lūn-bûn
@nan
2012 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2012 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
name
Lewis acid trapping of an elus ...... diate using scandium triflate.
@ast
Lewis acid trapping of an elus ...... diate using scandium triflate.
@en
type
label
Lewis acid trapping of an elus ...... diate using scandium triflate.
@ast
Lewis acid trapping of an elus ...... diate using scandium triflate.
@en
prefLabel
Lewis acid trapping of an elus ...... diate using scandium triflate.
@ast
Lewis acid trapping of an elus ...... diate using scandium triflate.
@en
P2093
P2860
P50
P356
P1476
Lewis acid trapping of an elus ...... diate using scandium triflate.
@en
P2093
Beatrice Braun
Enrico Miceli
Erik Farquhar
Florian Felix Pfaff
Kallol Ray
Uwe Kuhlmann
P2860
P304
14710-14713
P356
10.1021/JA306674H
P407
P577
2012-08-31T00:00:00Z