Combined experimental and theoretical study on the reductive cleavage of inert C-O bonds with silanes: ruling out a classical Ni(0)/Ni(II) catalytic couple and evidence for Ni(I) intermediates.
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Recent advances in homogeneous nickel catalysisMetal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsNickel-Catalyzed Arylation of Heteroaryl-containing Diarylmethanes: Exceptional Reactivity of the Ni(NIXANTPHOS)-based Catalyst.When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl HalidesBond cleavage of lignin model compounds into aromatic monomers using supported metal catalysts in supercritical water.The cross-dehydrogenative coupling of C(sp3)-H bonds: a versatile strategy for C-C bond formations.Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation.Metal catalyzed defunctionalization reactions.Transition-metal catalyzed valorization of lignin: the key to a sustainable carbon-neutral future.Nickel-Catalyzed Cross-Coupling Reactions of Unreactive Phenolic Electrophiles via C-O Bond Activation.Complexes of Ni(i): a "rare" oxidation state of growing importance.Enantioselective, nickel-catalyzed Suzuki cross-coupling of quinolinium ions.Halide Abstraction Competes with Oxidative Addition in the Reactions of Aryl Halides with [Ni(PMen Ph(3-n) )4 ].Nickel-catalyzed trifluoromethylthiolation of Csp2-O bonds.An unusual example of hypervalent silicon: a five-coordinate silyl group bridging two palladium or nickel centers through a nonsymmetrical four-center two-electron bond.Mild sp2Carbon-Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory.Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments.Lewis Acid Accelerated Aryl Ether Bond Cleavage with Nickel: Orders of Magnitude Rate Enhancement Using AlMe3.Versatile (η6-arene)Ni(PCy3) nickel monophosphine precursors.Reductive Homocoupling of Organohalides Using Nickel(II) Chloride and Samarium Metal.Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species.Cross-Coupling of Organolithium with Ethers or Aryl Ammonium Salts by C-O or C-N Bond Cleavage.Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study.Mechanism of Ni N-heterocyclic carbene catalyst for C-O bond hydrogenolysis of diphenyl ether: a density functional study.Mechanistic Study on Nickel-Catalyzed Silylation of Aryl Methyl Ethers.Hydride & dihydrogen complexes of earth abundant metals: structure, reactivity, and applications to catalysis.Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides.Forging C-C Bonds Through Decarbonylation of Aryl Ketones.Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage.Nickel-Catalyzed Heck-Type Monofluoroacetation of Styrenes for Facile Synthesis of Allylic Fluorides.Nickel-catalyzed C-N bond reduction of aromatic and benzylic quaternary ammonium triflates.Metal-catalyzed dealkoxylative C(aryl)-C(sp3) cross-coupling-replacement of aromatic methoxy groups of aryl ethers by employing a functionalized nucleophile.Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis.Preparation of Vinyl Arenes by Nickel-Catalyzed Reductive Coupling of Aryl Halides with Vinyl Bromides.Cross-coupling polycondensation via C-O or C-N bond cleavage.Nickel-Catalyzed Alkoxy-Alkyl Interconversion with Alkylborane Reagents through C-O Bond Activation of Aryl and Enol Ethers.Carboxyl radical-assisted 1,5-aryl migration through Smiles rearrangement.How and Why Does Ni(0) Promote Smooth Etheric C-O Bond Cleavage and C-C Bond Formation? A Theoretical Study.
P2860
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P2860
Combined experimental and theoretical study on the reductive cleavage of inert C-O bonds with silanes: ruling out a classical Ni(0)/Ni(II) catalytic couple and evidence for Ni(I) intermediates.
description
2013 nî lūn-bûn
@nan
2013 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2013 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
name
Combined experimental and theo ...... dence for Ni(I) intermediates.
@ast
Combined experimental and theo ...... dence for Ni(I) intermediates.
@en
type
label
Combined experimental and theo ...... dence for Ni(I) intermediates.
@ast
Combined experimental and theo ...... dence for Ni(I) intermediates.
@en
prefLabel
Combined experimental and theo ...... dence for Ni(I) intermediates.
@ast
Combined experimental and theo ...... dence for Ni(I) intermediates.
@en
P2093
P50
P356
P1476
Combined experimental and theo ...... idence for Ni(I) intermediates
@en
P2093
Enrique Gómez-Bengoa
Josep Cornella
Ruben Martin
P304
P356
10.1021/JA311940S
P407
P577
2013-01-23T00:00:00Z