Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center. Evidence for an Fe(IV)=O oxidant.
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Intramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesStructures, metal ion affinities, and fluorescence properties of soluble derivatives of tris((6-phenyl-2-pyridyl)methyl)amine.Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds.Iron complexes of dendrimer-appended carboxylates for activating dioxygen and oxidizing hydrocarbons.Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes.Copper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenesAromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.Discrete complexes immobilized onto click-SBA-15 silica: controllable loadings and the impact of surface coverage on catalysisSecondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach.Direct observation of a nonheme iron(IV)-oxo complex that mediates aromatic C-F hydroxylation.Iron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation.Microsolvation of methyl hydrogen peroxide: ab initio quantum chemical approach.Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H2O2.Intramolecular aromatic amination through iron-mediated nitrene transfer.Alcohol oxidation with H2O2 catalyzed by a cheap and promptly available imine based iron complex.New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands.Electron deficient nonplanar β-octachlorovanadylporphyrin as a highly efficient and selective epoxidation catalyst for olefins.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?CopperII-mediated aromatic ortho-hydroxylation: a hybrid DFT and AB initio exploration.On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex.Reactivity of copper(ii)-alkylperoxo complexes
P2860
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P2860
Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center. Evidence for an Fe(IV)=O oxidant.
description
2003 nî lūn-bûn
@nan
2003 թուականի Փետրուարին հրատարակուած գիտական յօդուած
@hyw
2003 թվականի փետրվարին հրատարակված գիտական հոդված
@hy
2003年の論文
@ja
2003年論文
@yue
2003年論文
@zh-hant
2003年論文
@zh-hk
2003年論文
@zh-mo
2003年論文
@zh-tw
2003年论文
@wuu
name
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@ast
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@en
type
label
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@ast
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@en
prefLabel
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@ast
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@en
P2093
P356
P1476
Biomimetic aryl hydroxylation ...... dence for an Fe(IV)=O oxidant.
@en
P2093
Emily L Que
Lawrence Que
Mark P Mehn
Michael P Jensen
Steven J Lange
P304
P356
10.1021/JA028478L
P407
P577
2003-02-01T00:00:00Z