Remarkable stereocontrol in the polymerization of racemic lactide using aluminum initiators supported by tetradentate aminophenoxide ligands.
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Ring-Opening Polymerization of rac-Lactide with Aluminum Chiral Anilido-Oxazolinate ComplexesZinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide.Synthesis of isotactic-heterotactic stereoblock (hard-soft) poly(lactide) with tacticity control through immortal coordination polymerization.Group 4 metal complexes of Trost's semi-crown ligand: synthesis, structural characterization and studies on the ring-opening polymerization of lactides and ε-caprolactone.Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures.Stereocontrolled ring-opening polymerisation of lactide.Beyond stereoselectivity, switchable catalysis: some of the last frontier challenges in ring-opening polymerization of cyclic esters.Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters.Major impact of N-methylation on cytotoxicity and hydrolysis of salan Ti(IV) complexes: sterics and electronics are intertwined.Metal-size influence in iso-selective lactide polymerization.The effect of steric changes on the isoselectivity of dinuclear indium catalysts for lactide polymerization.Monomeric Ti(IV) homopiperazine complexes and their exploitation for the ring opening polymerisation of rac-lactide.8-Quinolinolato gallium complexes: iso-selective initiators for rac-lactide polymerization.Synthesis and structural characterization of well-defined anionic aluminum alkoxide complexes supported by NON-type diamido ether tridentate ligands and their use for the controlled ROP of lactide.Discrete divalent rare-earth cationic ROP catalysts: ligand-dependent redox behavior and discrepancies with alkaline-earth analogues in a ligand-assisted activated monomer mechanism.Monomethylaluminum and dimethylaluminum pyrrolylaldiminates for the ring-opening polymerization of rac-lactide: effects of ligand structure and coordination geometry.Replacing tin in lactide polymerization: design of highly active germanium-based catalysts.Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides.Syntheses of bis(pyrrolylaldiminato)aluminum complexes for the polymerisation of lactide.Synergistic empirical and theoretical study on the stereoselective mechanism for the aluminum salalen complex mediated polymerization of rac-lactide.Imino phenoxide complexes of niobium and tantalum as catalysts for the polymerization of lactides, ε-caprolactone and ethylene.Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-lactide.Magnesium, zinc and aluminium complexes supported by tripodal diaminebis(aryloxido) ligands: synthesis, solid state and solution structure.Mononuclear salen-gallium complexes for iso-selective ring-opening polymerization (ROP) of rac-lactide.Selective Synthesis of Cyclic Carbonate by Salalen-Aluminum Complexes and Mechanistic Studies.Bimetallic salen aluminum complexes: cooperation between reactive centers in the ring-opening polymerization of lactides and epoxides.Isotactic rac-Lactide Polymerization with Copper Complexes: The Influence of Complex Nuclearity.A closer look at ε-caprolactone polymerization catalyzed by alkyl aluminum complexes: the effect of induction period on overall catalytic activity.Mechanistic Insight into the Stereochemical Control of Lactide Polymerization by Salan-Aluminum Catalysts.Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes.Synthesis and characterisation of unsymmetrical Zr(IV) amine tris(phenolate) complexes and their application in ROP of rac-LA.Heterometallic aluminates: alkali metals trapped by an aluminium aryloxide claw.C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.Chiral (1,2)-diphenylethylene-salen complexes of triel metals: coordination patterns and mechanistic considerations in the isoselective ROP of lactide.Group 4 Metal Complexes of Phenylene-Salalen Ligands in rac-Lactide Polymerization Giving High Molecular Weight Stereoblock Poly(lactic acid).Highly Active and Iso-Selective Catalysts for the Ring-Opening Polymerization of Cyclic Esters using Group 2 Metal Initiators.Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Functional Racemic β-Lactones.Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization.A new route for the preparation of enriched iso-polylactide from rac-lactide via a Lewis acid catalyzed ring-opening of an epoxide.Different mechanisms at different temperatures for the ring-opening polymerization of lactide catalyzed by binuclear magnesium and zinc alkoxides.
P2860
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P2860
Remarkable stereocontrol in the polymerization of racemic lactide using aluminum initiators supported by tetradentate aminophenoxide ligands.
description
2004 nî lūn-bûn
@nan
2004 թուականի Մարտին հրատարակուած գիտական յօդուած
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2004 թվականի մարտին հրատարակված գիտական հոդված
@hy
2004年の論文
@ja
2004年学术文章
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2004年学术文章
@zh-cn
2004年学术文章
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2004年学术文章
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2004年学术文章
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2004年學術文章
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name
Remarkable stereocontrol in th ...... entate aminophenoxide ligands.
@ast
Remarkable stereocontrol in th ...... entate aminophenoxide ligands.
@en
type
label
Remarkable stereocontrol in th ...... entate aminophenoxide ligands.
@ast
Remarkable stereocontrol in th ...... entate aminophenoxide ligands.
@en
prefLabel
Remarkable stereocontrol in th ...... entate aminophenoxide ligands.
@ast
Remarkable stereocontrol in th ...... entate aminophenoxide ligands.
@en
P2093
P356
P1476
Remarkable stereocontrol in th ...... dentate aminophenoxide ligands
@en
P2093
Andrew J P White
David J Williams
Edward L Marshall
Vernon C Gibson
P304
P356
10.1021/JA038757O
P407
P577
2004-03-01T00:00:00Z