Benzothiazoline: versatile hydrogen donor for organocatalytic transfer hydrogenation.Low-valent niobium-catalyzed reduction of alpha,alpha,alpha-trifluorotoluenes.Expeditious synthesis of benzopyrans via Lewis acid-catalyzed C-H functionalization: remarkable enhancement of reactivity by an ortho substituent.Enantioselective Friedel-Crafts alkylation of indoles, pyrroles, and furans with trifluoropyruvate catalyzed by chiral phosphoric acid.Chiral phosphoric acid-catalyzed oxidative kinetic resolution of indolines based on transfer hydrogenation to imines.Chiral copper(II) phosphate catalyzed enantioselective synthesis of isochromene derivatives by sequential intramolecular cyclization and asymmetric transfer hydrogenation of o-alkynylacetophenones.Enantioselective Mannich-type reaction catalyzed by a chiral Brønsted acid.Brønsted acid-catalyzed Nazarov cyclization of pyrrole derivatives accelerated by microwave irradiation.Enantioselective Robinson-type annulation reaction catalyzed by chiral phosphoric acids.Low-valent niobium-mediated double activation of C-F/C-H bonds: fluorene synthesis from o-arylated alpha,alpha,alpha-trifluorotoluene derivatives.Enantiodivergent Atroposelective Synthesis of Chiral Biaryls by Asymmetric Transfer Hydrogenation: Chiral Phosphoric Acid Catalyzed Dynamic Kinetic Resolution.Niobium(v)-catalyzed defluorinative triallylation of α,α,α-trifluorotoluene derivatives by triple C-F bond activation.Chiral Phosphoric Acid Catalyzed Kinetic Resolution of Indolines Based on a Self-Redox Reaction.Enantioselective synthesis of fused heterocycles with contiguous stereogenic centers by chiral phosphoric acid catalyzed symmetry breaking.Remarkable Differences in Reactivity between Benzothiazoline and Hantzsch Ester as a Hydrogen Donor in Chiral Phosphoric Acid Catalyzed Asymmetric Reductive Amination of Ketones.Chiral phosphoric acid catalyzed oxidative kinetic resolution of cyclic secondary amine derivatives including tetrahydroquinolines by hydrogen transfer to imines.Cu(I)-catalyzed enantioselective [2 + 2] cycloaddition of 1-methoxyallenylsilane with alpha-imino ester: chiral synthesis of alpha,beta-unsaturated acylsilanes.Enantioselective synthesis of multisubstituted biaryl skeleton by chiral phosphoric acid catalyzed desymmetrization/kinetic resolution sequence.B(C6F5)3-Catalyzed Hydrodesulfurization Using Hydrosilanes--Metal-Free Reduction of Sulfides.Highly diastereoselective synthesis of tricyclic fused-pyrans by sequential hydride shift mediated double C(sp3)-H bond functionalization.Enzymatic resolution of racemic 1,2:5,6-di-O-cyclohexylidene and 1,2:3,4-di-O-cyclohexylidene-myo-inositolNovel thermal reaction of Fischer carbene complexes with imines: synthesis of beta-methoxy allylic amine derivativesThe asymmetric [3 + 2] cycloaddition reaction of chiral alkenyl Fischer carbene complexes with imines: synthesis of optically pure 2,5-disubstituted-3-pyrrolidinonesA novel approach to 2-arylated quinolines: electrocyclization of alkynyl imines via vinylidene complexesChiral Brønsted acid-catalyzed inverse electron-demand aza Diels-Alder reactionChiral Brønsted acid catalyzed enantioselective aza-Diels-Alder reaction of Brassard's diene with iminesSynthesis of nitrogen-containing compounds using chromium Fischer carbene complexesChiral Brønsted acid catalyzed enantioselective Mannich-type reactionC-C coupling reactions of superstrong CF3 groups with C(sp2)-H bonds: reactivity and synthetic utility of zero-valent niobium catalystChiral phosphoric acid catalyzed enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes: cooperative effect of 3 A molecular sievesCu(I)-catalyzed enantioselective [3 + 2] cycloaddition reaction of 1-alkylallenylsilane with alpha-imino ester: asymmetric synthesis of dehydroproline derivativesStronger Brønsted acidsChiral Brønsted acid catalyzed enantioselective hydrophosphonylation of imines: asymmetric synthesis of alpha-amino phosphonatesMechanism of oil-in-water emulsification using a water-soluble amphiphilic polymer and lipophilic surfactantExpeditious construction of a carbobicyclic skeleton via sp3-C-H functionalization: hydride shift from an aliphatic tertiary position in an internal redox processConcise route to 3-arylisoquinoline skeleton by Lewis acid catalyzed C(sp3)-H bond functionalization and its application to formal synthesis of (±)-tetrahydropalmatineChiral phosphoric acid catalyzed enantioselective synthesis of β-amino-α,α-difluoro carbonyl compoundsEnantioselective aza-Darzens reaction catalyzed by a chiral phosphoric acidSelective activation of enantiotopic C(sp3)-hydrogen by means of chiral phosphoric acid: asymmetric synthesis of tetrahydroquinoline derivativesSynthesis of pyrroles: reaction of chromium N-alkylaminocarbene complexes with alpha,beta-unsaturated aldehydes
P50
Q38328164-32D8ECB8-2CDC-46C1-AEA4-EDBD0F4FC1E3Q42163647-CDF96034-8023-440A-9442-18CB0CF41DBDQ43123804-AE27CC97-36EB-4EE3-8CEF-6982552B1328Q43161095-C329B18C-1AC7-45D4-8A49-39245923E0E0Q43510241-45CCF29E-6598-4F60-9179-A6FB6DD8CB3AQ43656892-06DECAFD-4228-447E-BFAE-24327F8C0890Q44800284-9BF4A5EB-FD7C-4FEE-B600-440C8B98087BQ46008736-BBBA4C1B-E95D-46FB-BB09-B85751FBB04DQ46030869-A542B6F9-03BE-45CA-8B84-A9C77979798AQ46920276-266CB769-9349-4AF3-A721-D759EEEDF22AQ48127374-A610119B-3CF3-4801-853F-0194384DFB50Q48294677-314B8E38-7C49-4B8E-8EB2-21A2309FC533Q50886070-8BA43809-7B4E-4035-B0E1-49BEBF707A4FQ51712432-CD73C573-379F-4BFE-BF87-614CF37058C2Q53662603-CB6523DA-9C55-4C17-97E7-5B8625650C18Q53666986-6009E66D-F7A4-4CA6-B42D-48998D05612CQ53854864-6D4F5E2F-95CF-4A73-9E84-57B4E53EBD22Q54023176-BE1658A5-C6EB-4522-B670-B29938ED1B07Q54193697-1CE85457-4325-4825-8D9F-68E51996FA17Q64916014-580B0E78-653F-44FD-B2F7-538344E94A6DQ72178038-F1200A6A-AE80-4758-A97B-837EC6BB2460Q73032413-E01C88D0-28FB-484D-81FC-5E2009B3A388Q74221598-5F313EF8-7D96-4C0F-8DCD-34C4EE7DEFDAQ75351491-E5BBC430-4714-4F2A-BDEB-1A465645317CQ79180372-D3B2F1C2-2841-4F04-9AC4-882E8F9C7D28Q79776999-9239AE8E-DB07-4D71-8131-2E9D741F9D71Q80062053-3833D414-D2ED-4A4D-BCFC-43298B050716Q80261419-85D71322-7C5C-4065-93AF-26314343D52DQ80445438-F2E09FC6-7F15-4CAE-BDF2-6CB90A25DD5FQ81102136-4A8BB1B9-B7B9-4357-AEF8-513030A25B6EQ81507083-010F2755-3B55-44E7-9DAE-9B9CFC755379Q81553295-A376E0CA-92FD-4680-B154-293C228B32BEQ81855414-ABAE99E3-BC73-4347-A9AC-793B7266603EQ83321871-A8556E2B-A20E-409E-962C-B2AB251BBBE2Q83391487-1D899C59-1094-4A6C-BF47-2FFEFA552F71Q83571921-E2868E0C-E696-4B9F-BA98-D1ECE01A351FQ83579465-8282D65E-DFD7-4255-BCF6-0CBBC670DD4DQ83737329-38B2A924-BA78-4D68-AFB5-D17563E988FAQ83784023-623E1E62-E040-4E5F-9997-18E07FB0F519Q83827305-F46C56E9-0039-45E1-B796-7A6821F63CCE
P50
description
Japans onderzoeker
@nl
hulumtues
@sq
researcher
@en
հետազոտող
@hy
name
Takahiko Akiyama
@af
Takahiko Akiyama
@an
Takahiko Akiyama
@ast
Takahiko Akiyama
@bar
Takahiko Akiyama
@br
Takahiko Akiyama
@ca
Takahiko Akiyama
@co
Takahiko Akiyama
@cs
Takahiko Akiyama
@cy
Takahiko Akiyama
@da
type
label
Takahiko Akiyama
@af
Takahiko Akiyama
@an
Takahiko Akiyama
@ast
Takahiko Akiyama
@bar
Takahiko Akiyama
@br
Takahiko Akiyama
@ca
Takahiko Akiyama
@co
Takahiko Akiyama
@cs
Takahiko Akiyama
@cy
Takahiko Akiyama
@da
prefLabel
Takahiko Akiyama
@af
Takahiko Akiyama
@an
Takahiko Akiyama
@ast
Takahiko Akiyama
@bar
Takahiko Akiyama
@br
Takahiko Akiyama
@ca
Takahiko Akiyama
@co
Takahiko Akiyama
@cs
Takahiko Akiyama
@cy
Takahiko Akiyama
@da
P1053
B-9896-2017
P106
P1153
7403024252
P21
P27
P31
P3829
P496
0000-0003-4709-4107
P5029
read0044231
P569
2000-01-01T00:00:00Z
P735
P7783
200901007447424579