Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo spec

Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo spec

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http://www.wikidata.org/entity/Q31168326

Q31168326

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Photochemical production of a highly reactive porphyrin-iron-oxo species.Laser flash photolysis generation of high-valent transition metal-oxo species: insights from kinetic studies in real time.Highly reactive porphyrin-iron-oxo derivatives produced by photolyses of metastable porphyrin-iron(IV) diperchlorates Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways.Kinetics and mechanism of oxidation reactions of porphyrin-iron(IV)-oxo intermediates.Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.The influence of reversible trianionic pincer OCO(3-)μ-oxo Cr(IV) dimer formation ([Cr(IV)]2(μ-O)) and donor ligands in oxygen-atom-transfer (OAT).Detection of different oxidation states of individual manganese porphyrins during their reaction with oxygen at a solid/liquid interface.Acid-catalyzed disproportionation of oxoiron(IV) porphyrins to give oxoiron(IV) porphyrin radical cations.Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex.Photochemical generation and kinetic studies of a putative porphyrin-ruthenium(V)-oxo species.Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Reflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation Chemistry Trans-dioxo manganese(V) porphyrins.Photocatalytic aerobic oxidation by a bis-porphyrin-ruthenium(IV) mu-oxo dimer: observation of a putative porphyrin-ruthenium(V)-oxo intermediate.Production of a putative iron(V)-oxocorrole species by photo-disproportionation of a bis-corrole-diiron(IV)-mu-oxo dimer: implication for a green oxidation catalyst.Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution.Remarkable solvent, porphyrin ligand, and substrate effects on participation of multiple active oxidants in manganese(III) porphyrin catalyzed oxidation reactions.Selective C-H Halogenations with a Highly Fluorinated Manganese Porphyrin.Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.Ligand control in the photochemical generation of high-valent porphyrin-iron-oxo derivatives.A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds.Selective C−H Halogenation with a Highly Fluorinated Manganese Porphyrin

P2860

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P2860

Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo spec

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2005年の論文

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