H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
about
Carboranes in the chemist's toolbox.High yield C-derivatization of weakly coordinating carborane anions.The Strongest Acid: Protonation of Carbon Dioxide.Triethylsilyl Perfluoro-Tetraphenylborate, [Et(3)Si][F(20)-BPh(4)], a widely used Non-Existent Compound.The R3O+···H+ hydrogen bond: toward a tetracoordinate oxadionium(2+) ion.Evidence for C-H hydrogen bonding in salts of tert-butyl cation.The strongest Brønsted acid: protonation of alkanes by H(CHB(11)F(11)) at room temperatureA unified view to Brønsted acidity scales: do we need solvated protons?Reactive p-block cations stabilized by weakly coordinating anions.Wagner-Meerwein-Type Rearrangements of Germapolysilanes - A Stable Ion Study.Arylation of hydrocarbons enabled by organosilicon reagents and weakly coordinating anions.Quantum-chemical and electrochemical investigation of the electrochemical windows of halogenated carborate anions.Perhalogenated carba-closo-dodecaborate anions as ligand substituents: applications in gold catalysis.Hydrogen bonding versus hyperconjugation in condensed-phase carbocations.Copper-mediated C-C cross-coupling reaction of monocarba-closo-dodecaborate anion for the synthesis of functional molecules.H(OEt2)2[P(1,2-O2C6Cl4)3]: synthesis, characterization, and application as a single-component initiator for the carbocationic polymerization of olefins.Chemistry. Lewis acids with a difference.Isolation of a carborane-fused triazole radical anion.Dehydrogenation of icosahedral carborane anions via gas-phase collisional activation.Fusing N-heterocyclic carbenes with carborane anions.Synthesis of 13-vertex dimetallacarboranes by electrophilic insertion into 12-vertex ruthenacarboranes.Fusing Dicarbollide Ions with N-Heterocyclic Carbenes.Inductive effects of 10 and 12-vertex closo-carborane anions: cluster size and charge make a difference.Complexes of carborane acids linked by strong hydrogen bonds: acidity scales.Synthesis of a silylium zwitterion.Anionic and zwitterionic carboranyl N-heterocyclic carbene Au(i) complexes.The molecular and electronic structures of a thioaroyl cation formed by borinium ion-mediated C=S double bond cleavage of CS2.Synthesis of unsymmetrical N-carboranyl NHCs: directing effect of the carborane anion.Difunctionalized {closo-1-CB11 } clusters: 1- and 2-amino-12-ethynylcarba-closo-dodecaborates."Dumbbell"- and "Clackers"-Shaped Dimeric Derivatives of Monocarba-closo-dodecaborate.B-H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis.Fusing Carborane Carboxylic Acids with Alkynes: 3D Analogues of Isocoumarins via Regioselective B-H Activation.Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks.Formation of an Isolable Divinylborinium Ion through Twofold 1,2-Carboboration between a Diarylborinium Ion and Diphenylacetylene.The Me3 NB12 Cl11. Radical: A Strong One-Electron Oxidizing Agent.Synthesis of geodesic polynuclear arenes and fullerenes by intramolecular aryl-aryl coupling.Synthesis and full characterization of an iridium B-H activation intermediate of the monocarba-closo-dodecaborate anion.Convenient C-alkylation of the [HCB11Cl11]−carborane anionSynthesis and properties of the weakly coordinating anion [Me3 NB12 Cl11 ](-)Cation reduction and comproportionation as novel strategies to produce high voltage, halide free, carborane based electrolytes for rechargeable Mg batteries
P2860
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P2860
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
description
2010 nî lūn-bûn
@nan
2010 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@ast
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@en
type
label
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@ast
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@en
prefLabel
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@ast
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@en
P2860
P356
P1476
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
@en
P2093
Christopher A Reed
P2860
P304
P356
10.1021/AR900159E
P407
P577
2010-01-01T00:00:00Z