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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

http://www.wikidata.org/entity/Q34047988

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A synthetic molecular system capable of mirror-image genetic replication and transcription.Stochastic and empirical models of the absolute asymmetric synthesis by the Soai-autocatalysis.Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess.Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality.Spontaneous emergence of chirality in the limited enantioselectivity model: autocatalytic cycle driven by an external reagent.Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin.Spontaneous mirror symmetry breaking and origin of biological homochirality.The Role of Templating in the Emergence of RNA from the Prebiotic Chemical Mixture.Absolute asymmetric synthesis in enantioselective autocatalytic reaction networks: theoretical games, speculations on chemical evolution and perhaps a synthetic option.The Viedma deracemization of racemic conglomerate mixtures as a paradigm of spontaneous mirror symmetry breaking in aggregation and polymerization.Amplification of enantiomeric excess, mirror-image symmetry breaking and kinetic proofreading in Soai reaction models with different oligomeric orders.Effective potential and chiral symmetry breaking.Molecular Chirality in Meteorites and Interstellar Ices, and the Chirality Experiment on Board the ESA Cometary Rosetta Mission Asymmetric Chiral Growth of Micron-SizeNaClO3Crystals in Water Aerosols

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P2860

Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

http://www.wikidata.org/entity/Q34047988

description

2005 nî lūn-bûn

@nan

2005 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած

@hyw

2005 թվականի սեպտեմբերին հրատարակված գիտական հոդված

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2005年の論文

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2005年論文

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2005年論文

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2005年論文

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2005年論文

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2005年論文

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2005年论文

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name

Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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prefLabel

Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

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PNAS.0503171102

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Proceedings of the National Academy of Sciences of the United States of America

P1476

Mirror-symmetry breaking in the Soai reaction: a kinetic understanding

@en

P2093

Dominique Lavabre

http://www.w3.org/2001/XMLSchema#string

Haydée Rojas Cabrera

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Jean-Claude Micheau

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Jean-Michel Grevy

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Jesús Rivera Islas

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Ramón Hernández Lamoneda

http://www.w3.org/2001/XMLSchema#string

Thomas Buhse

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P2860

Absolute Asymmetric Synthesis: The Origin, Control, and Amplification of Chirality.

Chiral autocatalysis, spontaneous symmetry breaking, and stochastic behavior.

Asymmetric autocatalysis and its implications for the origin of homochirality.

Chiral symmetry breaking in sodium chlorate crystallizaton.

Chiral sign induction by vortices during the formation of mesophases in stirred solutions.

Solution structure and reagent binding of the zinc alkoxide catalyst in the Soai asymmetric autocatalytic reaction.

Kinetic evidence for a tetrameric transition state in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes.

Origins of asymmetric amplification in autocatalytic alkylzinc additions.

Reflections on spontaneous asymmetric synthesis by amplifying autocatalysis.

On spontaneous asymmetric synthesis

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10.1073/PNAS.0503171102

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39

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102

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1236534

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