Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin. - Wikidata - awgldk - TriplyDB

Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.

Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.

http://www.wikidata.org/entity/Q34300091

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Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities Late-Stage Fluorination: From Fundamentals to Application Radicals: Reactive Intermediates with Translational Potential Partial oxidation of light alkanes by periodate and chloride salts.Radiofluorination of a pre-formed gallium(III) aza-macrocyclic complex: towards next-generation positron emission tomography (PET) imaging agents.A convenient photocatalytic fluorination of unactivated C-H bonds.Targeted fluorination with the fluoride ion by manganese-catalyzed decarboxylation.Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis.Catalytic enantioselective cyclization and C3-fluorination of polyenes.Cafestol to Tricalysiolide B and Oxidized Analogues: Biosynthetic and Derivatization Studies Using Non-heme Iron Catalyst Fe(PDP).Enhanced reactivity in dioxirane C-H oxidations via strain release: a computational and experimental study Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds.Silver-catalyzed vinylogous fluorination of vinyl diazoacetates Organofluorine chemistry: Difluoromethylene motifs spaced 1,3 to each other imparts facial polarity to a cyclohexane ring.Oxidative aliphatic C-H fluorination with manganese catalysts and fluoride ion Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Introduction of fluorine and fluorine-containing functional groups.Late-stage formation of carbon-fluorine bonds.Synthetic biology for the directed evolution of protein biocatalysts: navigating sequence space intelligently.The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations.Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products.Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.Accessing Drug Metabolites via Transition-Metal Catalyzed C-H Oxidation: The Liver as Synthetic Inspiration.C-H functionalisation of cycloalkanes.A fluorinated dendrimer achieves excellent gene transfection efficacy at extremely low nitrogen to phosphorus ratios.Divergent mechanisms of iron-containing enzymes for hydrocarbon biosynthesis.Applications of Nonenzymatic Catalysts to the Alteration of Natural Products.Theoretical investigation of an ultrastable one dimensional infinite monatomic mixed valent gold wire with excellent electronic properties.Cooperative Light-Activated Iodine and Photoredox Catalysis for the Amination of Csp3 -H Bonds.Vanadium-Catalyzed C(sp(3))-H Fluorination Reactions.Asymmetric 18F-fluorination for applications in positron emission tomography.Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluoride Iron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion.Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution Site-Selective Aliphatic C-H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide.The Uranyl Cation as a Visible-Light Photocatalyst for C(sp(3) )-H Fluorination.The difluoromethylene (CF2) group in aliphatic chains: Synthesis and conformational preference of palmitic acids and nonadecane containing CF2 groups.Ligand-Enabled Stereoselective β-C(sp(3))-H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids.Crystal structure of chlorido-(5,10,15,20-tetra-phenyl-porphyrinato-κ(4) N)manganese(III) 2-amino-pyridine disolvate Hydrofluorination of Alkynes Catalysed by Gold Bifluorides.

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P2860

Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.

http://www.wikidata.org/entity/Q34300091

description

2012 nî lūn-bûn

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2012 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած

@hyw

2012 թվականի սեպտեմբերին հրատարակված գիտական հոդված

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2012年の論文

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2012年論文

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2012年論文

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2012年論文

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2012年論文

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2012年論文

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2012年论文

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

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SCIENCE.1222327

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Oxidative aliphatic C-H fluori ...... yzed by a manganese porphyrin.

@en

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John T Groves

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Mu-Jeng Cheng

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Robert J Nielsen

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Wei Liu

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William A Goddard

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Xiongyi Huang

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P2860

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density

Density-functional exchange-energy approximation with correct asymptotic behavior

Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides

The catalytic pathway of cytochrome p450cam at atomic resolution

Fluorine in pharmaceuticals: looking beyond intuition

Catalysis for fluorination and trifluoromethylation

A new mixing of Hartree–Fock and local density‐functional theories

Reactive oxygen species have a causal role in multiple forms of insulin resistance

A "push-pull" mechanism for heterolytic o-o bond cleavage in hydroperoxo manganese porphyrins.

Combined effects on selectivity in Fe-catalyzed methylene oxidation.

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1322-1325

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scholarly article

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10.1126/SCIENCE.1222327

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337

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2012-09-01T00:00:00Z

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22984066

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