Strategic redox relay enables a scalable synthesis of ouabagenin, a bioactive cardenolide.
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Scalable C-H Oxidation with Copper: Synthesis of PolyoxypregnanesPhotochemical Approaches to Complex Chemotypes: Applications in Natural Product SynthesisShort, Enantioselective Total Synthesis of Highly Oxidized TaxanesPalladium-Catalyzed Enantioselective Heck Alkenylation of Trisubstituted Allylic Alkenols: A Redox-Relay Strategy to Construct Vicinal StereocentersSynthesis of medicinally relevant terpenes: reducing the cost and time of drug discovery.Improving physical properties via C-H oxidation: chemical and enzymatic approachesInvestigating the nature of palladium chain-walking in the enantioselective redox-relay Heck reaction of alkenyl alcoholsAcademia-industry symbiosis in organic chemistry.Characterization of Cardiac Glycoside Natural Products as Potent Inhibitors of DNA Double-Strand Break Repair by a Whole-Cell Double Immunofluorescence Assay.Relative reactivity of alkenyl alcohols in the palladium-catalyzed redox-relay Heck reaction.Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systemsEnantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids.Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary StereocentersNatural product synthesis in the age of scalability.A practical and catalytic reductive olefin coupling.Two-phase synthesis of (-)-taxuyunnanine D.Oxidative Entry into the Illicium Sesquiterpenes: Enantiospecific Synthesis of (+)-Pseudoanisatin.Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.The synthesis of cardenolide and bufadienolide aglycones, and related steroids bearing a heterocyclic subunit.Synthesis of angularly substituted trans-fused hydroindanes by convergent coupling of acyclic precursors.A convergent total synthesis of ouabagenin.Concise Enantioselective Total Synthesis of Cardiotonic Steroids 19-Hydroxysarmentogenin and Trewianin Aglycone.Concise Enantioselective Synthesis of Oxygenated Steroids via Sequential Copper(II)-Catalyzed Michael Addition/Intramolecular Aldol Cyclization Reactions.Fe-Catalyzed C-C Bond Construction from Olefins via Radicals.A convergent total synthesis of 19-hydroxysarmentogenin.Two Enabling Strategies for the Stereoselective Conversion of Internal Alkynes into Trisubstituted Alkenes.Expedient and Diastereodivergent Assembly of Terpenoid Decalin Subunits having Quaternary Stereocenters through Organocatalytic Robinson Annulation of Nazarov Reagent.Natural products as inspiration for the development of new synthetic methods.Enantioselective Total Synthesis of Cannogenol-3-O-α-l-rhamnoside via Sequential Cu(II)-Catalyzed Michael Addition/Intramolecular Aldol Cyclization Reactions.Total Synthesis of Δ(12) -Prostaglandin J3 : Evolution of Synthetic Strategies to a Streamlined Process.Symmetry-Driven Strategy for the Assembly of the Core Tetracycle of (+)-Ryanodine: Synthetic Utility of a Cobalt-Catalyzed Olefin Oxidation and α-Alkoxy Bridgehead Radical Reaction.Concise total syntheses of amphidinolides C and F.Scalable synthesis enabling multilevel bio-evaluations of natural products for discovery of lead compounds.A diversity-oriented synthesis of bioactive benzanilides via a regioselective C(sp2)-H hydroxylation strategy.
P2860
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P2860
Strategic redox relay enables a scalable synthesis of ouabagenin, a bioactive cardenolide.
description
2013 nî lūn-bûn
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2013 թուականի Յունուարին հրատարակուած գիտական յօդուած
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2013 թվականի հունվարին հրատարակված գիտական հոդված
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2013年の論文
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年学术文章
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name
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@ast
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@en
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@nl
type
label
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@ast
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@en
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@nl
prefLabel
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@ast
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@en
Strategic redox relay enables ...... enin, a bioactive cardenolide.
@nl
P2860
P356
P1433
P1476
Strategic redox relay enables a scalable synthesis of ouabagenin, a bioactive cardenolide
@en
P2093
Hans Renata
Phil S Baran
P2860
P356
10.1126/SCIENCE.1230631
P407
P577
2013-01-01T00:00:00Z