Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
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Lithium Enolates Derived from Pyroglutaminol: Aggregation, Solvation, and AtropisomerismAsymmetric, stereodivergent synthesis of (-)-clusianone utilizing a biomimetic cationic cyclizationFacile formation of β-hydroxyboronate esters by a Cu-catalyzed diboration/Matteson homologation sequence.Solid-State and Solution Structures of Glycinimine-Derived Lithium Enolates.Structure-Reactivity Relationships in Lithiated Evans Enolates: Influence of Aggregation and Solvation on the Stereochemistry and Mechanism of Aldol AdditionsEvans Enolates: Solution Structures of Lithiated Oxazolidinone-Derived Enolates.Mechanism of Lithium Diisopropylamide-Mediated Ortholithiation of 1,4-Bis(trifluoromethyl)benzene under Nonequilibrium Conditions: Condition-Dependent Rate Limitation and Lithium Chloride-Catalyzed Inhibition.A Protocol for Safe Lithiation Reactions Using Organolithium Reagents.Lithium Enolates Derived from Weinreb Amides: Insights into Five-Membered Chelate RingsElectrophilic amination: the case of nitrenoids.Direct Asymmetric Alkylation of Ketones: Still Unconquered.Mixed Aggregates of the Dilithiated Koga Tetraamine: NMR Spectroscopic and Computational Studies.Microsolvation and sp(2)-stereoinversion of monomeric α-(2,6-di-tert-butylphenyl)vinyllithium as measured by NMR.Colloidal nanocrystals of lithiated group 14 elements.Accurate molecular weight determination of small molecules via DOSY-NMR by using external calibration curves with normalized diffusion coefficients.Cross-Coupling of Organolithium with Ethers or Aryl Ammonium Salts by C-O or C-N Bond Cleavage.Isolation and Characterization, Including by X-ray Crystallography, of Contact and Solvent-Separated Ion Pairs of Silenyl Lithium Species.Bis-(benzothiazol-2-yl)-amines and their metal amides: a structural comparison in the solid state.Functionalizations of Mixtures of Regioisomeric Aryllithium Compounds by Selective Trapping with Dichlorozirconocene.High-yield lithiation of azobenzenes by tin-lithium exchange.Unprecedented directed lateral lithiations of tertiary carbons on NHC platforms.Characterization of a multicomponent lithium lithiate from a combined x-ray diffraction, NMR spectroscopy, and computational approach.Understanding the directed ortho lithiation of (R)-Ph₂P(=NCO₂Me)NHCH(Me)Ph. NMR spectroscopic and computational study of the structure of the N-lithiated species.Combining Neopentyllithium with Potassium tert-Butoxide: Formation of an Alkane-Soluble Lochmann-Schlosser Superbase.Triangles and Squares for a Unique Molecular Crystal Structure: Unsupported Two-Coordinate Lithium Cations and CC Agostic Interactions in Cyclopropyllithium Derivatives.Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Arene Metalations.Controlling the Coordination Sphere of Alkyllithiums Results in Selective Reactions with Allylic Amines.Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks.Lithium Diisopropylamide: Nonequilibrium Kinetics and Lessons Learned about Rate Limitation.Lithium Hexamethyldisilazide-Mediated Enolization of Acylated Oxazolidinones: Solvent, Cosolvent, and Isotope Effects on Competing Monomer- and Dimer-Based Pathways.Lithium Halomethylcarbenoids: Preparation and Use in the Homologation of Carbon Electrophiles.Lithium Amino Alkoxide-Evans Enolate Mixed Aggregates: Aldol Addition with Matched and Mismatched Stereocontrol.Bioinspired total synthesis of tetrahydrofuran lignans by tandem nucleophilic addition/redox isomerization/oxidative coupling and cycloetherification reactions as key steps.2D 7Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings.Harnessing the ortho-directing ability of the azetidine ring for the regioselective and exhaustive functionalization of arenes.Case for Lithium Tetramethylpiperidide-Mediated Ortholithiations: Reactivity and Mechanisms.Simplifying metal-'ate' chemistry: formation and comprehensive characterisation of a homo-metallic amido lithiate complex.Chiral Lithiated Allylic α-Sulfonyl Carbanions: Experimental and Computational Study of Their Structure, Configurational Stability, and Enantioselective Synthesis.200 Years of Lithium and 100 Years of Organolithium Chemistry.Benchmarking lithium amide versus amine bonding by charge density and energy decomposition analysis arguments.
P2860
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P2860
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
description
2013 nî lūn-bûn
@nan
2013 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2013 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
name
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@ast
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@en
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@nl
type
label
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@ast
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@en
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@nl
prefLabel
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@ast
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@en
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@nl
P356
P1433
P1476
Role of organolithium aggregates and mixed aggregates in organolithium mechanisms.
@en
P2093
Hans J Reich
P304
P356
10.1021/CR400187U
P577
2013-08-13T00:00:00Z