Regioselective lithium diisopropylamide-mediated ortholithiation of 1-chloro-3-(trifluoromethyl)benzene: role of autocatalysis, lithium chloride catalysis, and reversibility.
about
Exceedingly Facile Ph-X Activation (X = Cl, Br, I) with Ruthenium(II): Arresting Kinetics, Autocatalysis, and MechanismsMechanisms of autocatalysis.Lithium diisopropylamide-mediated lithiation of 1,4-difluorobenzene under nonequilibrium conditions: role of monomer-, dimer-, and tetramer-based intermediates and lessons about rate limitation.Computational studies of lithium diisopropylamide deaggregation.Mechanism of Lithium Diisopropylamide-Mediated Ortholithiation of 1,4-Bis(trifluoromethyl)benzene under Nonequilibrium Conditions: Condition-Dependent Rate Limitation and Lithium Chloride-Catalyzed Inhibition.Lithium diisopropylamide-mediated ortholithiation of 2-fluoropyridines: rates, mechanisms, and the role of autocatalysis.Enediolate-dilithium amide mixed aggregates in the enantioselective alkylation of arylacetic acids: structural studies and a stereochemical model.Sodium Diisopropylamide in N,N-Dimethylethylamine: Reactivity, Selectivity, and Synthetic UtilityDevelopment of a web-based platform for studying lithiation reactions in silico.Azaaldol condensation of a lithium enolate solvated by N,N,N',N'-tetramethylethylenediamine: dimer-based 1,2-addition to imines.A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.Regioselective Transition-Metal-Free Allyl-Allyl Cross-Couplings.Functionalizations of Mixtures of Regioisomeric Aryllithium Compounds by Selective Trapping with Dichlorozirconocene.Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Arene Metalations.Lithium Diisopropylamide: Nonequilibrium Kinetics and Lessons Learned about Rate Limitation.Lithium Hexamethyldisilazide-Mediated Enolization of Acylated Oxazolidinones: Solvent, Cosolvent, and Isotope Effects on Competing Monomer- and Dimer-Based Pathways.Molecular salt effects in the gas phase: tuning the kinetic basicity of [HCCLiCl]⁻ and [HCCMgCl₂]⁻ by LiCl and MgCl₂.Harnessing the ortho-directing ability of the azetidine ring for the regioselective and exhaustive functionalization of arenes.Case for Lithium Tetramethylpiperidide-Mediated Ortholithiations: Reactivity and Mechanisms.After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne productsSplit Personality of Lithium Chloride: Recent Salt Effects in Organometallic RecipesEnhancing the function, non-additivity, and substitution position effect of the Li atom in the cation–π interaction and its mechanism: anab initiostudy of Li+ ··· Li-substituted benzene complexes
P2860
Q28829324-09522749-46DD-4783-8FB2-E23BA7CA1CC9Q34377759-0AC544CF-2F6A-4884-9A4C-4E78DCDE1756Q34764391-35199326-48D9-4E09-8612-0B6618AC9AFAQ35250701-E20C57B8-CBF4-4A09-97F2-F734E265C67AQ36677571-72C09DD0-A648-4A95-81BE-A0F6205CC8E6Q36816390-30D4C23D-2373-4F4F-BBE7-64D3DCB10D3BQ37282005-E6880EF0-8533-4AE3-B493-CA818E6A8E6DQ37591829-093AD399-BE04-4DEB-91B0-ECFEE683178DQ41156866-E61F8A24-A60C-4B00-AEDA-8442E6FA5A55Q43086061-27C3B40F-C1BA-49ED-9817-423DA2F71117Q45548011-48DA07B6-BE7F-4492-9187-2AF6392A730FQ46514696-FD639A19-3AFD-4968-A3E1-CFA9122468FFQ46636925-A7C7B674-2546-4231-B61C-8E99A9382F14Q48293156-35B356E8-863F-47A5-AA18-5A479027D84DQ48337425-4C9B32B2-910B-456D-8C61-F48EB9D730C5Q48358929-EBD09FBF-A741-4EF1-AF38-48CE073B22F7Q51062885-11B40A74-E7DE-4EEC-816A-C1836EBEDEE6Q51064415-50376026-51BD-4094-8941-5A8C486DFB82Q52625829-637E4AD7-9AA5-4CFD-8241-9B1B5BDF7351Q57960393-651B6336-417A-4F36-8156-78F9D778E583Q57960411-D1D10172-CB7F-4970-A1D5-3A1B36E9C9E7Q57965489-5173F330-66CB-4C7D-944E-564FBA622BE0
P2860
Regioselective lithium diisopropylamide-mediated ortholithiation of 1-chloro-3-(trifluoromethyl)benzene: role of autocatalysis, lithium chloride catalysis, and reversibility.
description
2011 nî lūn-bûn
@nan
2011 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Regioselective lithium diisopr ...... catalysis, and reversibility.
@ast
Regioselective lithium diisopr ...... catalysis, and reversibility.
@en
type
label
Regioselective lithium diisopr ...... catalysis, and reversibility.
@ast
Regioselective lithium diisopr ...... catalysis, and reversibility.
@en
prefLabel
Regioselective lithium diisopr ...... catalysis, and reversibility.
@ast
Regioselective lithium diisopr ...... catalysis, and reversibility.
@en
P2093
P2860
P356
P1476
Regioselective lithium diisopr ...... catalysis, and reversibility.
@en
P2093
Alexander C Hoepker
David B Collum
Lekha Gupta
Marc F Faggin
P2860
P304
P356
10.1021/JA200906Z
P407
P577
2011-04-18T00:00:00Z