Structural, spectroscopic, and reactivity models for the manganese catalases.
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Mn4Ca cluster in photosynthesis: where and how water is oxidized to dioxygenMononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligandsReactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate FrameworkMetal Ion Modeling Using Classical MechanicsPreparation and Structural Properties of In(III)-H Complexes.Synthesis, characterization, and reactivity studies of a water-soluble bis(alkoxo)(carboxylato)-bridged diMn(III) complex modeling the active site in catalase.Mn K-edge X-ray absorption studies of oxo- and hydroxo-manganese(IV) complexes: experimental and theoretical insights into pre-edge properties.Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways.[(H2O)(terpy)Mn(mu-O)2Mn(terpy)(OH2)](NO3)3 (terpy = 2,2':6,2''-terpyridine) and its relevance to the oxygen-evolving complex of photosystem II examined through pH dependent cyclic voltammetrySpectroscopic characterization and reactivity studies of a mononuclear nonheme Mn(III)-hydroperoxo complex.Tetra-μ-benzoato-bis-[(3-methyl-quinoline)copper(II)](Cu-Cu).An active dimanganese(III)-tyrosyl radical cofactor in Escherichia coli class Ib ribonucleotide reductase.Multifrequency Pulsed EPR Studies of Biologically Relevant Manganese(II) ComplexesX-ray Absorption and Emission Study of Dioxygen Activation by a Small-Molecule Manganese ComplexReaction landscape of a pentadentate N5-ligated Mn(II) complex with O2˙- and H2O2 includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)dimanganese(III,IV) species.Neuroprotection by Polynitrogen Manganese Complexes: Regulation of Reactive Oxygen Species-Related Pathways.Using small molecule complexes to elucidate features of photosynthetic water oxidationReflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation ChemistryModeling the syn disposition of nitrogen donors in non-heme diiron enzymes. Synthesis, characterization, and hydrogen peroxide reactivity of diiron(III) complexes with the syn N-donor ligand H2BPG2DEV.Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters.Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes.High-frequency and high-field electron paramagnetic resonance (HFEPR): a new spectroscopic tool for bioinorganic chemistry.Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species.Synthesis and Characterization of a Linear [Mn(3)(O(2)CMe)(4)(py)(8)] Complex.Multicopper oxidase involvement in both Mn(II) and Mn(III) oxidation during bacterial formation of MnO(2).EPR-ENDOR characterization of (17O, 1H, 2H) water in manganese catalase and its relevance to the oxygen-evolving complex of photosystem II.Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer.Role of the secondary coordination sphere in metal-mediated dioxygen activation.Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolutionUnsymmetrical bimetallic complexes with M(II)-(μ-OH)-M(III) cores (M(II)M(III) = Fe(II)Fe(III), Mn(II)Fe(III), Mn(II)Mn(III)): structural, magnetic, and redox properties.Heterobimetallic dioxygen activation: synthesis and reactivity of mixed Cu-Pd and Cu-Pt bis(mu-oxo) complexesCharacterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes.Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn(6)(mu(4)-O)(2)] Unit.Ligand modification transforms a catalase mimic into a water oxidation catalyst.Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.Metalloradical complexes of manganese and chromium featuring an oxidatively rearranged ligand.Ligand displacement for fixing manganese: relevance to cellular metal ion transport and synthesis of polymeric coordination complexes.A novel single-site manganese(II) complex of a pyridine derivative as a catalase mimetic for disproportionation of H2O2 in water.Calcium manganese oxides as oxygen evolution catalysts: O2 formation pathways indicated by 18O-labelling studies.Electrochemical formation of Mn(III)-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands.
P2860
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P2860
Structural, spectroscopic, and reactivity models for the manganese catalases.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年論文
@yue
2004年論文
@zh-hant
2004年論文
@zh-hk
2004年論文
@zh-mo
2004年論文
@zh-tw
2004年论文
@wuu
2004年论文
@zh
2004年论文
@zh-cn
name
Structural, spectroscopic, and reactivity models for the manganese catalases.
@ast
Structural, spectroscopic, and reactivity models for the manganese catalases.
@en
type
label
Structural, spectroscopic, and reactivity models for the manganese catalases.
@ast
Structural, spectroscopic, and reactivity models for the manganese catalases.
@en
prefLabel
Structural, spectroscopic, and reactivity models for the manganese catalases.
@ast
Structural, spectroscopic, and reactivity models for the manganese catalases.
@en
P356
P1433
P1476
Structural, spectroscopic, and reactivity models for the manganese catalases
@en
P2093
Vincent L Pecoraro
P304
P356
10.1021/CR020627V
P577
2004-02-01T00:00:00Z