How does single oxygen atom addition affect the properties of an Fe-nitrile hydratase analogue? The compensatory role of the unmodified thiolate.
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Catalytic Mechanism of Nitrile Hydratase Proposed by Time-resolved X-ray Crystallography Using a Novel Substrate, tert-ButylisonitrileStructure and mechanism of a nonhaem-iron SAM-dependent C-methyltransferase and its engineering to a hydratase and an O-methyltransferaseAnalyzing the catalytic role of active site residues in the Fe-type nitrile hydratase from Comamonas testosteroni Ni1Ru(II) complexes containing dmso and pyrazolyl ligands as catalysts for nitrile hydration in environmentally friendly media.Sulfur versus iron oxidation in an iron-thiolate model complexNitrile hydration by thiolate- and alkoxide-ligated Co-NHase analogues. Isolation of Co(III)-amidate and Co(III)-iminol intermediates.Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes.Use of metallopeptide based mimics demonstrates that the metalloprotein nitrile hydratase requires two oxidized cysteinates for catalytic activityUnderstanding how the thiolate sulfur contributes to the function of the non-heme iron enzyme superoxide reductase.Sulfur K-edge XAS and DFT studies on NiII complexes with oxidized thiolate ligands: implications for the roles of oxidized thiolates in the active sites of Fe and Co nitrile hydratase.Substrate binding preferences and pka determinations of a nitrile hydratase model complex: variable solvent coordination to [(bmmp-TASN)Fe]OTfComparative electronic structures of nitrogenase FeMoco and FeVco.Intermolecular disulfide bond to modulate protein function as a redox-sensing switch.Photooxidation of metal-bound thiolates: reactivity of sulfur containing peroxidic intermediates.Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer.Molecular dynamics simulations of the photoactive protein nitrile hydratase.Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate.Properties of square-pyramidal alkyl-thiolate Fe(III) complexes, including an analogue of the unmodified form of nitrile hydratase.Addition of dioxygen to an N4S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complexCharacterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes.Correlation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexesAdvances in the chemistry of oxaziridines.Bioinspired catalytic nitrile hydration by dithiolato, sulfinato/thiolato, and sulfenato/sulfinato ruthenium complexes.Multiple States of Nitrile Hydratase from Rhodococcus equi TG328-2: Structural and Mechanistic Insights from Electron Paramagnetic Resonance and Density Functional Theory Studies.Identification of clusters from reactions of ruthenium arene anticancer complex with glutathione using nanoscale liquid chromatography Fourier transform ion cyclotron mass spectrometry combined with (18)O-labeling.Bio-inspired nitrile hydration by peptidic ligands based on L-cysteine, L-methionine or L-penicillamine and pyridine-2,6-dicarboxylic acid.An S-Oxygenated [NiFe] Complex Modelling Sulfenate Intermediates of an O2 -Tolerant Hydrogenase.
P2860
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P2860
How does single oxygen atom addition affect the properties of an Fe-nitrile hydratase analogue? The compensatory role of the unmodified thiolate.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
2006年论文
@zh
2006年论文
@zh-cn
name
How does single oxygen atom ad ...... le of the unmodified thiolate.
@ast
How does single oxygen atom ad ...... le of the unmodified thiolate.
@en
type
label
How does single oxygen atom ad ...... le of the unmodified thiolate.
@ast
How does single oxygen atom ad ...... le of the unmodified thiolate.
@en
prefLabel
How does single oxygen atom ad ...... le of the unmodified thiolate.
@ast
How does single oxygen atom ad ...... le of the unmodified thiolate.
@en
P2093
P2860
P50
P356
P1476
How does single oxygen atom ad ...... ole of the unmodified thiolate
@en
P2093
Britt Hedman
Edward I Solomon
Jason Benedict
Keith O Hodgson
Priscilla Lugo-Mas
Steven D Davin
P2860
P304
11211-11221
P356
10.1021/JA062706K
P407
P577
2006-08-01T00:00:00Z