Application of donor/acceptor-carbenoids to the synthesis of natural products.
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Enantioselective carbenoid insertion into C(sp(3))-H bondsRecent advances in C(sp(3))-H bond functionalization via metal-carbene insertionsRecent applications of the divinylcyclopropane-cycloheptadiene rearrangement in organic synthesisBeyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes.Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol.Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction.Asymmetric Synthesis of Highly Functionalized Cyclopentanes by a Rhodium- and Scandium-Catalyzed Five-Step Domino Sequence.The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis.Computationally guided stereocontrol of the combined C-H functionalization/Cope rearrangementAsymmetric intramolecular α-cyclopropanation of aldehydes using a donor/acceptor carbene mimetic.Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols.Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts.Transition-metal-catalyzed aminations and aziridinations of C-H and C=C bonds with iminoiodinanes.Recent advances in the total synthesis of cyclopropane-containing natural products.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Ir-Catalyzed enantioselective group transfer reactions.Fluorinated diazoalkanes - a versatile class of reagents for the synthesis of fluorinated compounds.Recent advances in rhodium-catalyzed asymmetric synthesis of heterocycles.An entry to vinylcyclopropane through palladium-catalyzed intramolecular cyclopropanation of alkenes with unstabilized allylic tosylhydrazones.Applications of Nonenzymatic Catalysts to the Alteration of Natural Products.Recent progress in the catalytic carbene insertion reactions into the silicon-hydrogen bond.Copper-Catalyzed Formation of α-Alkoxycycloalkenones from N-Tosylhydrazones.Unusual reactions of diazocarbonyl compounds with α,β-unsaturated δ-amino esters: Rh(II)-catalyzed Wolff rearrangement and oxidative cleavage of N-H-insertion products.Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds.Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenesRhodium-catalyzed ring expansion of cyclopropanes to seven-membered rings by 1,5 C-C bond migration.Enantioselective intramolecular C-H insertion reactions of donor-donor metal carbenoids.Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate.Rhodium- and platinum-catalyzed [4+3] cycloaddition with concomitant indole annulation: synthesis of cyclohepta[b]indoles.Formal (4+1) cycloaddition of methylenecyclopropanes with 7-aryl-1,3,5-cycloheptatrienes by triple gold(I) catalysis.Stereoselective Radical C-H Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations.Synthesis of Benzodihydrofurans by Asymmetric C-H Insertion Reactions of Donor/Donor Rhodium Carbenes.Unveiling latent α-iminocarbene reactivity for intermolecular cascade reactions through alkyne oxidative amination.α-Diazo oxime ethers for N-heterocycle synthesis.Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes.Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.Asymmetric cyclopropanation of conjugated cyanosulfones using a novel cupreine organocatalyst: rapid access to δ(3)-amino acids.Palladium-Catalyzed Direct Cyclopropylation of Heterocycles.Iron-catalyzed intermolecular cycloaddition of diazo surrogates with hexahydro-1,3,5-triazines.
P2860
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P2860
Application of donor/acceptor-carbenoids to the synthesis of natural products.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@ast
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@en
type
label
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@ast
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@en
prefLabel
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@ast
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@en
P2860
P356
P1476
Application of donor/acceptor-carbenoids to the synthesis of natural products.
@en
P2093
Justin R Denton
P2860
P304
P356
10.1039/B901170F
P50
P577
2009-09-30T00:00:00Z