A Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 Antagonist

A Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 Antagonist

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http://www.wikidata.org/entity/Q36497550
Radical Smiles Rearrangement: An UpdateFree Radical Chemistry Enabled by Visible Light-Induced Electron Transfer.A new era for homolytic aromatic substitution: replacing Bu3SnH with efficient light-induced chain reactions.Photocatalysis in organic and polymer synthesis.Distal radical migration strategy: an emerging synthetic means.Efficient Aryl Migration from an Aryl Ether to a Carboxylic Acid Group To Form an Ester by Visible-Light Photoredox Catalysis.Metal-Free Intermolecular Aminoarylation of Alkynes.A photoredox-neutral Smiles rearrangement of 2-aryloxybenzoic acids.Synthesis of 1-Difluoroalkylated Isoquinolines via Palladium-Catalyzed Radical Cascade Difluoroalkylation-Cyclization of Vinyl Isocyanides with Bromodifluoroacetic Derivatives.Visible-light-induced aerobic dearomative reaction of indole derivatives: access to heterocycle fused or spirocyclo indolones.γ-Functionalizations of Amines through Visible-Light-Mediated, Redox-Neutral C-C Bond Cleavage.Carboxyl radical-assisted 1,5-aryl migration through Smiles rearrangement.Synthesis of the Privileged 8-Arylmenthol Class by Radical Arylation of Isopulegol.Visible-Light-Driven Photocatalytic Transformation of α,β-Unsaturated-N-Tosylhydrazones: A Novel Route to Allylic Sulfones
P2860

A Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 Antagonist

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http://www.wikidata.org/entity/Q36497550
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2015 nî lūn-bûn
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name
A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
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A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
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type
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A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
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A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
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A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
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A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
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P1433
P1476
P2093
P2860
P304
P31
P356
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P478
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P577
P698
P932
P356
P1433
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A Visible-Light-Mediated Radic ...... d Spirocyclic ORL-1 Antagonist
@en
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698
P932