Non-enzymatic and enzymatic hydrolysis of alkyl halides: a haloalkane dehalogenation enzyme evolved to stabilize the gas-phase transition state of an SN2 displacement reaction
about
The importance of reactant positioning in enzyme catalysis: a hybrid quantum mechanics/molecular mechanics study of a haloalkane dehalogenaseSubstrate specificity of fluoroacetate dehalogenase: an insight from crystallographic analysis, fluorescence spectroscopy, and theoretical computationsPerspective on Diabatic Models of Chemical Reactivity as Illustrated by the Gas-Phase S(N)2 Reaction of Acetate Ion with 1,2-DichloroethaneComparison of formation of reactive conformers for the SN2 displacements by CH3CO2- in water and by Asp124-CO2- in a haloalkane dehalogenase.Mechanisms and free energies of enzymatic reactions.Computer simulations of enzyme catalysis: finding out what has been optimized by evolution.Functionally relevant motions of haloalkane dehalogenases occur in the specificity-modulating cap domainsElectrostatic origin of the catalytic power of enzymes and the role of preorganized active sites.Stable carbon isotope fractionation during degradation of dichloromethane by methylotrophic bacteria.
P2860
Q24652411-03018306-CAEC-4E42-9B5F-9182319C86C6Q27679528-137E61C8-AE49-41BF-9B6D-1EF1E00F0F56Q33521728-1CF83019-A131-4012-B9B3-DC028C8A9AC9Q34803865-9EF8D2F3-8CD7-4596-B577-A39F6542BB11Q35768462-5AE3AEBA-14EE-4183-9053-25FC1044AB99Q36255425-1D7ABD15-0AE5-47F9-A41A-FE267570CA96Q36639249-B73390A3-E197-49A5-BA62-9E473579A214Q46509084-78B25861-2779-4458-96C7-0140A596AF36Q46846927-5813D840-DA92-45F0-9F93-DB7CBC9F3049
P2860
Non-enzymatic and enzymatic hydrolysis of alkyl halides: a haloalkane dehalogenation enzyme evolved to stabilize the gas-phase transition state of an SN2 displacement reaction
description
1997 nî lūn-bûn
@nan
1997年の論文
@ja
1997年論文
@yue
1997年論文
@zh-hant
1997年論文
@zh-hk
1997年論文
@zh-mo
1997年論文
@zh-tw
1997年论文
@wuu
1997年论文
@zh
1997年论文
@zh-cn
name
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@ast
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@en
type
label
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@ast
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@en
prefLabel
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@ast
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@en
P2093
P2860
P356
P1476
Non-enzymatic and enzymatic hy ...... f an SN2 displacement reaction
@en
P2093
A H Maulitz
F C Lightstone
T C Bruice
P2860
P304
P356
10.1073/PNAS.94.16.8417
P407
P50
P577
1997-08-01T00:00:00Z