Transition metal-mediated P-C/X exchange at bound phosphine ligands (X=aryl, alkyl, NR2, OR and F): scope and mechanisms.
about
A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction.Synthesis of fluorinated building blocks by transition-metal-mediated hydrodefluorination reactions.Imidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts.An efficient route to chiral N-heterocycles bearing a C-F stereogenic center via asymmetric hydrogenation of fluorinated isoquinolines.Consecutive C-F bond activation and C-F bond formation of heteroaromatics at rhodium: the peculiar role of FSi(OEt)3.R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate.Pd-Catalyzed Cyanation of (Hetero)Aryl Halides by Using Biphosphine Ligands.Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C-F Activation Steps at a Lewis Acidic Aluminum Fluoride.Unprecedented One-Pot Reaction towards Chiral, Non-Racemic Copper(I) Complexes of [2.2]Paracyclophane-Based P,N-Ligands.Synthesis and reductive elimination of arylPd(ii) trifluoromethyl complexes: a remarkable concentration effect on chemoselectivity.Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation.Non-symmetric diphosphines based on the imidazole scaffold: an unusual group interchange involving Pd-CH3 and (imidazole)P-Ph cleavage.Palladium-catalyzed direct synthesis of phosphole derivatives from triarylphosphines through cleavage of carbon-hydrogen and carbon-phosphorus bonds.Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation.Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane.Aryl-Phenyl Scrambling in Intermediate Organopalladium Complexes: A Gas-Phase Study of the Mizoroki-Heck Reaction
P2860
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P2860
Transition metal-mediated P-C/X exchange at bound phosphine ligands (X=aryl, alkyl, NR2, OR and F): scope and mechanisms.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
2006年论文
@zh
2006年论文
@zh-cn
name
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@ast
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@en
type
label
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@ast
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@en
prefLabel
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@ast
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@en
P2860
P356
P1476
Transition metal-mediated P-C/ ...... and F): scope and mechanisms.
@en
P2093
Stuart A Macgregor
P2860
P356
10.1039/B516248N
P577
2006-09-27T00:00:00Z